Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012506327> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2012506327 endingPage "1713" @default.
- W2012506327 startingPage "1707" @default.
- W2012506327 abstract "The five-coordinate compound [RuHCl(CO)(PiPr2Ph)2] (1), which was prepared from RuCl3· 3 H2O and PiPr2Ph in methanol in the presence of NEt3, reacts with CO and with diazoalkanes RCHN2 (R = Ph, H) to give the six-coordinate complexes [RuHCl(CO)2(PiPr2Ph)2] (4) and [RuHCl(CO)(=CHR)(PiPr2Ph)2] (5, 6), respectively. If the reaction of 1 with CH2N2, which at –78 °C affords 6, is carried out at room temperature, the ionic compound [MePiPr2Ph][RuHCl2(CO)(PiPr2Ph)2] (7) is formed. The corresponding PPN salt was obtained from 1 and [PPN]Cl. The X-ray crystal structure analysis of 7 revealed, that the anionic species [RuHCl2(CO)(PiPr2Ph)2]− contains the chloro ligands in cis and the phosphanes in trans disposition. The Ru=CH2 bond of compound 6 is quite labile and, therefore, the CH2 unit is easily displaced by CO or pyridine. From 1 and pyridine, an isomeric mixture of [RuHCl(CO)(py)(PiPr2Ph)2] (9a, b) is formed. Treatment of 1 with HC≡CR (R = H, Ph) yields the five-coordinate vinylruthenium(II) complexes [Ru(CH=CHR)Cl(CO)(PiPr2Ph)2] (12, 13) by insertion of the alkyne into the Ru–H bond. The preparation of [RuHX(CO)-(PiPr2Ph)2] (X = CF3CO2, I) is also reported." @default.
- W2012506327 created "2016-06-24" @default.
- W2012506327 creator A5008133817 @default.
- W2012506327 creator A5013393550 @default.
- W2012506327 creator A5067323975 @default.
- W2012506327 creator A5086562220 @default.
- W2012506327 date "1999-10-01" @default.
- W2012506327 modified "2023-10-11" @default.
- W2012506327 title "Hydrido(carbonyl) and Hydrido(carbene) Complexes of Ruthenium" @default.
- W2012506327 cites W1514484834 @default.
- W2012506327 cites W1963540910 @default.
- W2012506327 cites W1997907468 @default.
- W2012506327 cites W2019940535 @default.
- W2012506327 cites W2026525277 @default.
- W2012506327 cites W2030801499 @default.
- W2012506327 cites W2039772159 @default.
- W2012506327 cites W2051815915 @default.
- W2012506327 cites W2053535968 @default.
- W2012506327 cites W2064153195 @default.
- W2012506327 cites W2068704439 @default.
- W2012506327 cites W2072148697 @default.
- W2012506327 cites W2076383598 @default.
- W2012506327 cites W2085978059 @default.
- W2012506327 cites W2113123503 @default.
- W2012506327 cites W2113382588 @default.
- W2012506327 cites W2148066840 @default.
- W2012506327 cites W2164328498 @default.
- W2012506327 cites W2169149564 @default.
- W2012506327 cites W2317952575 @default.
- W2012506327 cites W2953048711 @default.
- W2012506327 doi "https://doi.org/10.1002/(sici)1099-0682(199910)1999:10<1707::aid-ejic1707>3.0.co;2-y" @default.
- W2012506327 hasPublicationYear "1999" @default.
- W2012506327 type Work @default.
- W2012506327 sameAs 2012506327 @default.
- W2012506327 citedByCount "17" @default.
- W2012506327 countsByYear W20125063272014 @default.
- W2012506327 countsByYear W20125063272016 @default.
- W2012506327 countsByYear W20125063272017 @default.
- W2012506327 countsByYear W20125063272018 @default.
- W2012506327 countsByYear W20125063272020 @default.
- W2012506327 crossrefType "journal-article" @default.
- W2012506327 hasAuthorship W2012506327A5008133817 @default.
- W2012506327 hasAuthorship W2012506327A5013393550 @default.
- W2012506327 hasAuthorship W2012506327A5067323975 @default.
- W2012506327 hasAuthorship W2012506327A5086562220 @default.
- W2012506327 hasConcept C115624301 @default.
- W2012506327 hasConcept C145148216 @default.
- W2012506327 hasConcept C155647269 @default.
- W2012506327 hasConcept C161790260 @default.
- W2012506327 hasConcept C178790620 @default.
- W2012506327 hasConcept C185592680 @default.
- W2012506327 hasConcept C2182769 @default.
- W2012506327 hasConcept C2776371256 @default.
- W2012506327 hasConcept C2777164566 @default.
- W2012506327 hasConcept C2779012754 @default.
- W2012506327 hasConcept C2779485729 @default.
- W2012506327 hasConcept C2779607525 @default.
- W2012506327 hasConcept C2779782174 @default.
- W2012506327 hasConcept C555196967 @default.
- W2012506327 hasConcept C71240020 @default.
- W2012506327 hasConcept C8010536 @default.
- W2012506327 hasConceptScore W2012506327C115624301 @default.
- W2012506327 hasConceptScore W2012506327C145148216 @default.
- W2012506327 hasConceptScore W2012506327C155647269 @default.
- W2012506327 hasConceptScore W2012506327C161790260 @default.
- W2012506327 hasConceptScore W2012506327C178790620 @default.
- W2012506327 hasConceptScore W2012506327C185592680 @default.
- W2012506327 hasConceptScore W2012506327C2182769 @default.
- W2012506327 hasConceptScore W2012506327C2776371256 @default.
- W2012506327 hasConceptScore W2012506327C2777164566 @default.
- W2012506327 hasConceptScore W2012506327C2779012754 @default.
- W2012506327 hasConceptScore W2012506327C2779485729 @default.
- W2012506327 hasConceptScore W2012506327C2779607525 @default.
- W2012506327 hasConceptScore W2012506327C2779782174 @default.
- W2012506327 hasConceptScore W2012506327C555196967 @default.
- W2012506327 hasConceptScore W2012506327C71240020 @default.
- W2012506327 hasConceptScore W2012506327C8010536 @default.
- W2012506327 hasIssue "10" @default.
- W2012506327 hasLocation W20125063271 @default.
- W2012506327 hasOpenAccess W2012506327 @default.
- W2012506327 hasPrimaryLocation W20125063271 @default.
- W2012506327 hasRelatedWork W1981725732 @default.
- W2012506327 hasRelatedWork W2001652473 @default.
- W2012506327 hasRelatedWork W2004824042 @default.
- W2012506327 hasRelatedWork W2012506327 @default.
- W2012506327 hasRelatedWork W2056785211 @default.
- W2012506327 hasRelatedWork W2085968741 @default.
- W2012506327 hasRelatedWork W2737858382 @default.
- W2012506327 hasRelatedWork W2950188710 @default.
- W2012506327 hasRelatedWork W2952687896 @default.
- W2012506327 hasRelatedWork W3014202192 @default.
- W2012506327 hasVolume "1999" @default.
- W2012506327 isParatext "false" @default.
- W2012506327 isRetracted "false" @default.
- W2012506327 magId "2012506327" @default.
- W2012506327 workType "article" @default.