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- W2012506549 abstract "A variety of experimental data obtained from single crystals and powders of zirconia has been examined to obtain the stability limits of the tetragonal and monoclinic phases. These limits are used to delineate the possible modes of transformation at different temperatures in the light of a nonclassical theory of nucleation. The theory predicts an asymmetric relation between three critical temperatures T∗, T0, and Tc. Transformation by nucleation and growth occurs only in the range T0-Tc during cooling and in the range T∗-T0 during heating. Below Tc, transformation proceeds homogeneously in a manner akin to spinodal decomposition. In the neighborhood of Tc, the metastable tetragonal phase can have a long lifetime. It is assumed that the driving mechanism of transformation comes from the partial softening of a particular shear mode of lattice vibration. An indirect evidence in support of this assumption comes from the linear relationship between the transformation temperature of a zirconia/hafnia solid solution and the reciprocal effective cation mass." @default.
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- W2012506549 date "1988-05-01" @default.
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- W2012506549 title "Stability limits in the monoclinic-tetragonal transformations of zirconia" @default.
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- W2012506549 doi "https://doi.org/10.1016/0378-4363(88)90123-4" @default.
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