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- W2012508557 abstract "The synthesis of 2-C-branched erythritol derivatives, including the plant sugar (±)-2-C-methylerythritol 2, was achieved through a dihydroxylation/reduction sequence on a series of 4-substituted 1,2-dioxines 3. The asymmetric dihydroxylation of 1,2-dioxines was examined, providing access to optically enriched dihydroxy 1,2-dioxanes 4. The synthesized 1,2-dioxanes were converted to other erythro sugar analogues and tetrahydrofurans through controlled cleavage of the endoperoxide linkage." @default.
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- W2012508557 date "2009-05-29" @default.
- W2012508557 modified "2023-09-25" @default.
- W2012508557 title "Dihydroxylation of 4-Substituted 1,2-Dioxines: A Concise Route to Branched Erythro Sugars" @default.
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- W2012508557 doi "https://doi.org/10.1021/jo900669u" @default.
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