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- W2012509306 abstract "The facile total synthesis of the (−)-Heliconol A (ent-1) as well as its diastereoisomer 18 is described, in which different reaction sequences lead to different results. The osmylation of 15 followed by hydrolysis afforded a single isomer 18, otherwise, a mixture of ent-1 and 18 resulted. Other important processes include the catalytic asymmetric CBS reduction and induced osmylation. The synthesis proceeded with a sequence of 11 steps, affording ent-1 in 9.0% and 18 in 22% overall yield, respectively." @default.
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- W2012509306 date "2007-10-01" @default.
- W2012509306 modified "2023-10-18" @default.
- W2012509306 title "Facile total synthesis of the (−)-Heliconol A" @default.
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- W2012509306 doi "https://doi.org/10.1016/j.tet.2007.07.053" @default.
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