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• W2012524972 startingPage "032113" @default.
• W2012524972 abstract "Aluminum-based alloy hydride Al2CuHx (x ∼ 1) is synthesized by hydrogenating Al2Cu alloy using high-temperature and high-pressure hydrogen atmosphere. Al8Cu square antiprisms in Al2Cu twist around the c axis of a tetragonal unit cell by hydrogenation. The twist enlarges the interstitial spaces for accommodating hydrogen atoms which align linearly parallel to the c axis in Al2CuHx. Thermodynamic stability of Al2CuHx results from the balance of stabilization by H 1s and Al 3sp hybridization and destabilization owing to the Fermi-level lifting upon hydrogenation. The crystal and electronic structures of Al2CuHx illustrate the formation of an interstitial hydride of aluminum-based alloy." @default.
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• W2012524972 date "2013-09-01" @default.
• W2012524972 modified "2023-10-14" @default.
• W2012524972 title "Synthesis and formation process of Al₂CuH_<i>x</i>: A new class of interstitial aluminum-based alloy hydride" @default.
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• W2012524972 doi "https://doi.org/10.1063/1.4821632" @default.
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