FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012558702> ?p ?o ?g. }

• W2012558702 endingPage "3817" @default.
• W2012558702 startingPage "3811" @default.
• W2012558702 abstract "In contrast to the high stability of N-alkyl-N-cyclopropylamine derivatives, N-cyclopropyl-N-phenylamine (1a) has been found to slowly convert into the hitherto unknown product N-(1,2-dioxolan-3-yl)-N-phenylamine (1f) at room temperature under aerobic conditions. The rate of this conversion was found to be significantly increased by the presence of a catalytic amount of the single-electron oxidizing agent tris(1,10-phenanthroline)FeIII hexafluorophosphate or of the hydrogen-abstracting agents benzoyl peroxide or tert-butyl peroxide/UV light. Based on the regio- and stereochemical outcomes of aerobic ring-opening reactions of some specifically ring-methylated derivatives of 1a, namely N-(1-methylcyclopropyl)-N-phenylamine (2a), N-(trans-2-methylcyclopropyl)-N-phenylamine (3a), and N-(cis-2-methylcyclopropyl)-N-phenylamine (4a), as well as other experimental evidence, an autocatalytic mechanism analogous to that of the oxygenation of vinylcyclopropanes is proposed for the formation of the 1,2-dioxolane product. The oxidative radical ring opening and related chemistry of these novel derivatives could be valuable in mechanistic studies of heteroatom-oxidizing enzymes." @default.
• W2012558702 created "2016-06-24" @default.
• W2012558702 creator A5034468612 @default.
• W2012558702 creator A5060927652 @default.
• W2012558702 creator A5062714207 @default.
• W2012558702 date "2001-10-01" @default.
• W2012558702 modified "2023-10-07" @default.
• W2012558702 title "Autocatalytic Radical Ring Opening ofN-Cyclopropyl-N-phenylamines Under Aerobic Conditions − Exclusive Formation of the Unknown Oxygen Adducts,N-(1,2-Dioxolan-3-yl)-N-phenylamines" @default.
• W2012558702 cites W1521546861 @default.
• W2012558702 cites W1965820145 @default.
• W2012558702 cites W1966557643 @default.
• W2012558702 cites W1972494402 @default.
• W2012558702 cites W1973567978 @default.
• W2012558702 cites W1981225395 @default.
• W2012558702 cites W1982801303 @default.
• W2012558702 cites W1991414578 @default.
• W2012558702 cites W1992140046 @default.
• W2012558702 cites W2003828911 @default.
• W2012558702 cites W2006294648 @default.
• W2012558702 cites W2018174887 @default.
• W2012558702 cites W2023677845 @default.
• W2012558702 cites W2023978397 @default.
• W2012558702 cites W2034020828 @default.
• W2012558702 cites W2034932643 @default.
• W2012558702 cites W2035834248 @default.
• W2012558702 cites W2036839834 @default.
• W2012558702 cites W2044187258 @default.
• W2012558702 cites W2055613629 @default.
• W2012558702 cites W2057819683 @default.
• W2012558702 cites W2058756282 @default.
• W2012558702 cites W2060275098 @default.
• W2012558702 cites W2069933184 @default.
• W2012558702 cites W2071209845 @default.
• W2012558702 cites W2083395886 @default.
• W2012558702 cites W2087515126 @default.
• W2012558702 cites W2088231799 @default.
• W2012558702 cites W2091808919 @default.
• W2012558702 cites W2091840451 @default.
• W2012558702 cites W2097697619 @default.
• W2012558702 cites W2950144029 @default.
• W2012558702 cites W2950734109 @default.
• W2012558702 cites W2952783771 @default.
• W2012558702 cites W2952898255 @default.
• W2012558702 cites W2953066545 @default.
• W2012558702 cites W3004727183 @default.
• W2012558702 doi "https://doi.org/10.1002/1099-0690(200110)2001:20<3811::aid-ejoc3811>3.0.co;2-6" @default.
• W2012558702 hasPublicationYear "2001" @default.
• W2012558702 type Work @default.
• W2012558702 sameAs 2012558702 @default.
• W2012558702 citedByCount "42" @default.
• W2012558702 countsByYear W20125587022012 @default.
• W2012558702 countsByYear W20125587022014 @default.
• W2012558702 countsByYear W20125587022015 @default.
• W2012558702 countsByYear W20125587022016 @default.
• W2012558702 countsByYear W20125587022017 @default.
• W2012558702 countsByYear W20125587022018 @default.
• W2012558702 countsByYear W20125587022019 @default.
• W2012558702 countsByYear W20125587022020 @default.
• W2012558702 countsByYear W20125587022021 @default.
• W2012558702 countsByYear W20125587022022 @default.
• W2012558702 countsByYear W20125587022023 @default.
• W2012558702 crossrefType "journal-article" @default.
• W2012558702 hasAuthorship W2012558702A5034468612 @default.
• W2012558702 hasAuthorship W2012558702A5060927652 @default.
• W2012558702 hasAuthorship W2012558702A5062714207 @default.
• W2012558702 hasConcept C108204754 @default.
• W2012558702 hasConcept C155647269 @default.
• W2012558702 hasConcept C161790260 @default.
• W2012558702 hasConcept C178790620 @default.
• W2012558702 hasConcept C185592680 @default.
• W2012558702 hasConcept C20950531 @default.
• W2012558702 hasConcept C2780378348 @default.
• W2012558702 hasConcept C2781048764 @default.
• W2012558702 hasConcept C37263863 @default.
• W2012558702 hasConcept C533411734 @default.
• W2012558702 hasConcept C71240020 @default.
• W2012558702 hasConcept C77176794 @default.
• W2012558702 hasConceptScore W2012558702C108204754 @default.
• W2012558702 hasConceptScore W2012558702C155647269 @default.
• W2012558702 hasConceptScore W2012558702C161790260 @default.
• W2012558702 hasConceptScore W2012558702C178790620 @default.
• W2012558702 hasConceptScore W2012558702C185592680 @default.
• W2012558702 hasConceptScore W2012558702C20950531 @default.
• W2012558702 hasConceptScore W2012558702C2780378348 @default.
• W2012558702 hasConceptScore W2012558702C2781048764 @default.
• W2012558702 hasConceptScore W2012558702C37263863 @default.
• W2012558702 hasConceptScore W2012558702C533411734 @default.
• W2012558702 hasConceptScore W2012558702C71240020 @default.
• W2012558702 hasConceptScore W2012558702C77176794 @default.
• W2012558702 hasIssue "20" @default.
• W2012558702 hasLocation W20125587021 @default.
• W2012558702 hasOpenAccess W2012558702 @default.
• W2012558702 hasPrimaryLocation W20125587021 @default.
• W2012558702 hasRelatedWork W1575852573 @default.
• W2012558702 hasRelatedWork W2006766742 @default.
• W2012558702 hasRelatedWork W2036956123 @default.
• W2012558702 hasRelatedWork W2357322967 @default.
• W2012558702 hasRelatedWork W2496188727 @default.

• next