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- W2012592527 abstract "Comparison of powder X-ray diffraction data from a 2-2 wt% antimony-substituted calcium fluorapatite [0.185 Sb atoms per unit cell containing CaloF2(PO4)6] with data from an undoped sample shows electron density changes corresponding to antimony substitution at the Ca(2) (mirror) site. Many properties of this 2.2 wt% Sb sample indicate that it corresponds to commercial halophosphate phosphors of lower Sb concentration. Differing properties are shown by a 3.1 wt% Sb sample for which no diffraction evidence is found for substitution at the Ca(2) site, but for which electron density difference maps do suggest substitution at the Wyckoff 2(c) and 2(d) sites of P63/m, between Ca(l) (threefold) positions. Both Rietveld refinements and Fourier inversion of the differences between observed intensities were used to reach these conclusions." @default.
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- W2012592527 date "1991-10-01" @default.
- W2012592527 modified "2023-10-14" @default.
- W2012592527 title "Determination of the antimony substitution site in calcium fluorapatite from powder X-ray diffraction data" @default.
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- W2012592527 doi "https://doi.org/10.1107/s0108768191004986" @default.
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