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• W2012596953 abstract "The one-electron reduction of methyl viologen (MV2+) mediated by the carbon dioxide radical anion (CO2•-) during photocatalytic reactions in a colloidal TiO2 aqueous solution (pH 2) has been investigated by time-resolved absorption spectroscopy. The formation of MV•+ generated from the one-electron reduction reaction with CO2•-, which is generated from the one-electron oxidation reactions with the photogenerated holes (h+), was directly observed. The spectral features of the photogenerated charge carriers and the kinetic analysis of the formation process of MV•+ revealed that the CO2•-, desorbed from the surface, reacts with MV2+ via a homogeneous electron-transfer process in the bulk solution." @default.
• W2012596953 created "2016-06-24" @default.
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• W2012596953 date "2004-09-28" @default.
• W2012596953 modified "2023-10-14" @default.
• W2012596953 title "Direct Observation of the One-Electron Reduction of Methyl Viologen Mediated by the CO₂ Radical Anion during TiO₂ Photocatalytic Reactions" @default.
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• W2012596953 doi "https://doi.org/10.1021/la048100w" @default.
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• W2012596953 hasPublicationYear "2004" @default.
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