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• W201259977 abstract "We report on the discovery of a new solid, presumably amorphous n-butanol at ambient pressure. According to the literature data the melting point Tm of n-butanol is 183 K and the glass transition temperature Tg is 118 K. If kept isothermally at a fixed temperature between 130 and 160 K, the supercooled liquid n-butanol undergoes remarkable phase transformations to a solid phase. The new phase converts to liquid at a temperature of about 170 K. It is presumably amorphous because foreign substances dissolved in liquid n-butanol keep the same state in this new phase of butanol. The kinetics of free radical oxidation by dissolved oxygen in both solid amorphous phases is investigated in detail." @default.
• W201259977 created "2016-06-24" @default.
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• W201259977 date "2005-03-01" @default.
• W201259977 modified "2023-09-27" @default.
• W201259977 title "On the number of amorphous phases in n-butanol" @default.
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• W201259977 doi "https://doi.org/10.1016/j.jnoncrysol.2005.01.035" @default.
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