Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012601195> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2012601195 endingPage "424" @default.
- W2012601195 startingPage "419" @default.
- W2012601195 abstract "Here evidence is provided for the promotion effect of iron on methanol formation on PdX zeolite catalysts. The high activity and selectivity for methanol formation are markedly superior to those observed either on non-promoted Pd or on Fe zeolite. The activation energy obtained for the optimum promoted zeolite catalyst is close to those observed on other oxide supports. It is suggested that the zeolite framework does not primarily influence the reaction path. The promotion effect is attributed to the presence of PdFe bimetallic particles located mainly inside the cages and their migration is hindered by Fe2+ ions. This is the first report on the formation of iron-containing bimetallic particles inside zeolite cages. The optimum atomic ratio for promotion is found at Fe : Pd = 0.07, and the catalyst with Fe : Pd = 0.2 still displays excellent catalytic performance. Above Fe : Pd = 0.3 formation of a separate α-iron phase is suggested, since the activity and selectivity for methanol drops and higher hydrocarbons are formed." @default.
- W2012601195 created "2016-06-24" @default.
- W2012601195 creator A5017459108 @default.
- W2012601195 creator A5046676542 @default.
- W2012601195 creator A5052820707 @default.
- W2012601195 creator A5067491206 @default.
- W2012601195 date "1990-01-01" @default.
- W2012601195 modified "2023-10-16" @default.
- W2012601195 title "Promotion effect of Fe on the selectivity of Pd zeolite-X in methanol synthesis" @default.
- W2012601195 cites W1965878501 @default.
- W2012601195 cites W1976458677 @default.
- W2012601195 cites W1978979180 @default.
- W2012601195 cites W1981437121 @default.
- W2012601195 cites W1989874281 @default.
- W2012601195 cites W1993509765 @default.
- W2012601195 cites W2001366090 @default.
- W2012601195 cites W2004281577 @default.
- W2012601195 cites W2007624721 @default.
- W2012601195 cites W2008280882 @default.
- W2012601195 cites W2016236648 @default.
- W2012601195 cites W2022262620 @default.
- W2012601195 cites W2024879410 @default.
- W2012601195 cites W2032325332 @default.
- W2012601195 cites W2039723611 @default.
- W2012601195 cites W2045758388 @default.
- W2012601195 cites W2046057825 @default.
- W2012601195 cites W2046321888 @default.
- W2012601195 cites W2054183785 @default.
- W2012601195 cites W2059934768 @default.
- W2012601195 cites W2062990393 @default.
- W2012601195 cites W2069822358 @default.
- W2012601195 cites W2073576309 @default.
- W2012601195 cites W2074841311 @default.
- W2012601195 cites W2082063295 @default.
- W2012601195 cites W2087165996 @default.
- W2012601195 cites W2091467859 @default.
- W2012601195 cites W2093826936 @default.
- W2012601195 cites W2102134687 @default.
- W2012601195 cites W2129533293 @default.
- W2012601195 doi "https://doi.org/10.1039/ft9908600419" @default.
- W2012601195 hasPublicationYear "1990" @default.
- W2012601195 type Work @default.
- W2012601195 sameAs 2012601195 @default.
- W2012601195 citedByCount "17" @default.
- W2012601195 countsByYear W20126011952017 @default.
- W2012601195 crossrefType "journal-article" @default.
- W2012601195 hasAuthorship W2012601195A5017459108 @default.
- W2012601195 hasAuthorship W2012601195A5046676542 @default.
- W2012601195 hasAuthorship W2012601195A5052820707 @default.
- W2012601195 hasAuthorship W2012601195A5067491206 @default.
- W2012601195 hasConcept C118792377 @default.
- W2012601195 hasConcept C127413603 @default.
- W2012601195 hasConcept C161790260 @default.
- W2012601195 hasConcept C178790620 @default.
- W2012601195 hasConcept C179104552 @default.
- W2012601195 hasConcept C185592680 @default.
- W2012601195 hasConcept C2778077586 @default.
- W2012601195 hasConcept C2779607525 @default.
- W2012601195 hasConcept C42360764 @default.
- W2012601195 hasConcept C43411465 @default.
- W2012601195 hasConceptScore W2012601195C118792377 @default.
- W2012601195 hasConceptScore W2012601195C127413603 @default.
- W2012601195 hasConceptScore W2012601195C161790260 @default.
- W2012601195 hasConceptScore W2012601195C178790620 @default.
- W2012601195 hasConceptScore W2012601195C179104552 @default.
- W2012601195 hasConceptScore W2012601195C185592680 @default.
- W2012601195 hasConceptScore W2012601195C2778077586 @default.
- W2012601195 hasConceptScore W2012601195C2779607525 @default.
- W2012601195 hasConceptScore W2012601195C42360764 @default.
- W2012601195 hasConceptScore W2012601195C43411465 @default.
- W2012601195 hasIssue "2" @default.
- W2012601195 hasLocation W20126011951 @default.
- W2012601195 hasOpenAccess W2012601195 @default.
- W2012601195 hasPrimaryLocation W20126011951 @default.
- W2012601195 hasRelatedWork W1991722793 @default.
- W2012601195 hasRelatedWork W2004562227 @default.
- W2012601195 hasRelatedWork W2041840250 @default.
- W2012601195 hasRelatedWork W2080070073 @default.
- W2012601195 hasRelatedWork W2356348989 @default.
- W2012601195 hasRelatedWork W2379154166 @default.
- W2012601195 hasRelatedWork W2910451569 @default.
- W2012601195 hasRelatedWork W3037628611 @default.
- W2012601195 hasRelatedWork W4206421175 @default.
- W2012601195 hasRelatedWork W4302759529 @default.
- W2012601195 hasVolume "86" @default.
- W2012601195 isParatext "false" @default.
- W2012601195 isRetracted "false" @default.
- W2012601195 magId "2012601195" @default.
- W2012601195 workType "article" @default.