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- W2012606795 abstract "Abstract Group IV organometallic halides, (CH 3 ) n MX 4- n , (M = Si, Ge, Sn; n = 0-3, X = usually Cl but also Br), react with R f CCMgY (R f = CF 3 , CF 2 CF 3 , CF (CF 3 ) 2 ) to give the appropriate Group IV perfluoroalkynyl derivatives, (CH 3 ) n M (CCR f ) 4- n , (not all combinations of R f , n , and M are described). CH 3 SiCl 3 is an exception in that it yields only (CH 3 ) 2 Si(CCCF 3 ) 2 and not the expected product CH 3 Si(CCCF 3 ) 3 . The silicon and germanium derivatives are hydrolytically and thermally stable: the tin derivatives are not. Some spectroscopic properties of the new derivatives are described and discussed." @default.
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- W2012606795 date "1971-07-01" @default.
- W2012606795 modified "2023-09-27" @default.
- W2012606795 title "Perfluoroalkynyl derivatives II. The preparation of some group IV compounds" @default.
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- W2012606795 doi "https://doi.org/10.1016/s0022-1139(00)82532-4" @default.
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