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- W2012607839 abstract "Abstract At about 200°C, synthetic magnetites are oxidised to maghemites without any significant changes in morphology and surface area. This oxidation is accompanied by a contraction of the cubic unit cell. During oxidation the excess Fe probably moves towards the surface and combines with oxygen to form a film of maghemite, the thickness of which increases with time. The data on changes in Fe(II) content during the oxidation can be fitted to an equation describing the diffusion in a sphere. At 190°C the diffusion coefficients of Fe are in the range 0.8 to 2.1 × 10−15 cm2/sec and decrease with the increasing isomorphous substitution of Co, Ni and Zn for Fe(II) in the magnetite." @default.
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- W2012607839 date "1977-01-01" @default.
- W2012607839 modified "2023-09-26" @default.
- W2012607839 title "Mechanism of the low temperature oxidation of synthetic magnetites" @default.
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- W2012607839 doi "https://doi.org/10.1016/0022-1902(77)80523-x" @default.
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