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- W2012617523 abstract "Abstract Organic-inorganic materials comprising CO2-philic components may yield superior CO2 transport properties and good CO2/H2 gas selectivity. We report that a fine balance in size heterogeneity in the silicon-based structures is essential and a mixture of sizes up to 50 nm surrounded by 5–15 nm silicon-based nanostructures is the preferred inorganic phase morphology that yields optimal nanohybrid membranes. The combination of optimal synthesis conditions i.e. water/silicon ratio, condensation and ozone pre-treatment durations yields a nanohybrid membrane with a CO2 permeability of 2000 Barrer while achieving a CO2/H2 selectivity of 11. The findings of this work are important for the design of gas separation membranes using green materials." @default.
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- W2012617523 date "2012-01-01" @default.
- W2012617523 modified "2023-09-30" @default.
- W2012617523 title "Molecular design of nanohybrid gas separation membranes for optimal CO2 separation" @default.
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- W2012617523 doi "https://doi.org/10.1016/j.polymer.2011.12.011" @default.
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