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- W2012625969 abstract "Abstract Two novel polyoxometalate(POM)-templated coordination polymers: [Cu2(phnz)3][M6O19] (M = Mo for 1, W for 2; phnz = phenazine), have been hydrothermally synthesized and characterized by routine physical methods and single crystal X-ray diffraction. In the compounds, Lindqvist POMs as templates induce the [Cu2(phnz)3] complexes to 2D hexagonal metal-organic framework (MOF), which represents 63 topologies of dimensions ca. 13.515 × 13.515 × 13.515 A. Furthermore, the 2D sheets are held together by Lindqvist POMs into 3D supramolecular networks with 1D channel, and Lindqvist POMs site in the channels. The successful syntheses and isolation of two compounds provide a novel example of the utility of POM clusters as templates for self-assembly extended framework with cavities." @default.
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- W2012625969 date "2009-02-01" @default.
- W2012625969 modified "2023-10-16" @default.
- W2012625969 title "Assembly of two novel Lindqvist polyoxoanion-templated coordination polymers with standard honeycomb cavities" @default.
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- W2012625969 doi "https://doi.org/10.1016/j.solidstatesciences.2008.07.007" @default.
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