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- W2012626677 abstract "The VO2+ crossover, or permeability, through Nafion in a vanadium redox flow battery (VRFB) was monitored as a function of sulfuric acid concentration and VO2+ concentration. A vanadium rich solution was flowed on one side of the membrane through a flow field while symmetrically on the other side a blank or vanadium deficit solution was flowed. The blank solution was flowed through an electron paramagnetic resonance (EPR) cavity and the VO2+ concentration was determined from the intensity of the EPR signal. Concentration values were fit using a solution of Fick's law that allows for the effect of concentration change on the vanadium rich side. The fits resulted in permeability values of VO2+ ions across the membrane. Viscosity measurements of many VO2+ and H2SO4 solutions were made at 30–60°C. These viscosity values were then used to determine the effect of the viscosity of the flowing solution on the permeability of the ion." @default.
- W2012626677 created "2016-06-24" @default.
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- W2012626677 date "2013-01-01" @default.
- W2012626677 modified "2023-10-16" @default.
- W2012626677 title "Concentration Dependence of VO<sup>2+</sup>Crossover of Nafion for Vanadium Redox Flow Batteries" @default.
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- W2012626677 doi "https://doi.org/10.1149/2.004306jes" @default.
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