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- W2012637779 endingPage "1086" @default.
- W2012637779 startingPage "1076" @default.
- W2012637779 abstract "Abstract The correlation between the molecular design of a conjugated polyelectrolyte (CPE) and its aggregated structure and the emissive properties in water is systematically investigated by means of UV–vis spectrometry, fluorescence spectroscopy, and scanning/transmission electron microscopy. Five different and rationally designed CPEs having carboxylic acid side chains are synthesized. All five conjugated polyelectrolytes are seemingly completely soluble in water in visual observation. However, their quantum yields are dramatically different, changing from 0.45 to 51.4%. Morphological analysis by electron microscopy combined with fluorescence spectrophotometry reveals that the CPEs form self‐assembled aggregates at the nanoscale depending on the nature of their side chains. The feature of the self‐assembled aggregates directly determines the emissive property of the CPEs. The nature and the length of the spacer between the carboxylic acid group and the CPE backbone have a strong influence on the quantum yield of the CPEs. Our study demonstrates that bulky and hydrophilic side chains and spacers are required to achieve complete water‐solubility and high quantum yield of CPEs in water, providing an important molecular design principle to develop functional CPEs." @default.
- W2012637779 created "2016-06-24" @default.
- W2012637779 creator A5039472466 @default.
- W2012637779 creator A5041163341 @default.
- W2012637779 creator A5063632576 @default.
- W2012637779 date "2012-01-09" @default.
- W2012637779 modified "2023-10-12" @default.
- W2012637779 title "Design Principle of Conjugated Polyelectrolytes to Make Them Water-Soluble and Highly Emissive" @default.
- W2012637779 cites W1897959932 @default.
- W2012637779 cites W1963595345 @default.
- W2012637779 cites W1964058675 @default.
- W2012637779 cites W1964294948 @default.
- W2012637779 cites W1964862061 @default.
- W2012637779 cites W1964927509 @default.
- W2012637779 cites W1965044705 @default.
- W2012637779 cites W1965340007 @default.
- W2012637779 cites W1972078733 @default.
- W2012637779 cites W1975183641 @default.
- W2012637779 cites W1977997663 @default.
- W2012637779 cites W1980094416 @default.
- W2012637779 cites W1981696091 @default.
- W2012637779 cites W1982842302 @default.
- W2012637779 cites W1989313387 @default.
- W2012637779 cites W1990009882 @default.
- W2012637779 cites W1991280623 @default.
- W2012637779 cites W1991687045 @default.
- W2012637779 cites W1994373246 @default.
- W2012637779 cites W1995724714 @default.
- W2012637779 cites W1998179757 @default.
- W2012637779 cites W2001256666 @default.
- W2012637779 cites W2004664692 @default.
- W2012637779 cites W2005240816 @default.
- W2012637779 cites W2005502779 @default.
- W2012637779 cites W2008377368 @default.
- W2012637779 cites W2011894495 @default.
- W2012637779 cites W2012232321 @default.
- W2012637779 cites W2013880185 @default.
- W2012637779 cites W2018674897 @default.
- W2012637779 cites W2022408312 @default.
- W2012637779 cites W2024607050 @default.
- W2012637779 cites W2027261603 @default.
- W2012637779 cites W2031232992 @default.
- W2012637779 cites W2034805255 @default.
- W2012637779 cites W2035147376 @default.
- W2012637779 cites W2035275238 @default.
- W2012637779 cites W2039411266 @default.
- W2012637779 cites W2039673832 @default.
- W2012637779 cites W2040112959 @default.
- W2012637779 cites W2040759542 @default.
- W2012637779 cites W2043706032 @default.
- W2012637779 cites W2051357892 @default.
- W2012637779 cites W2054646907 @default.
- W2012637779 cites W2056148800 @default.
- W2012637779 cites W2057247529 @default.
- W2012637779 cites W2058312969 @default.
- W2012637779 cites W2059397441 @default.
- W2012637779 cites W2059998218 @default.
- W2012637779 cites W2064325362 @default.
- W2012637779 cites W2065826828 @default.
- W2012637779 cites W2068971720 @default.
- W2012637779 cites W2069653700 @default.
- W2012637779 cites W2072402969 @default.
- W2012637779 cites W2076997081 @default.
- W2012637779 cites W2079498434 @default.
- W2012637779 cites W2080258678 @default.
- W2012637779 cites W2081446942 @default.
- W2012637779 cites W2081483583 @default.
- W2012637779 cites W2081499738 @default.
- W2012637779 cites W2081950169 @default.
- W2012637779 cites W2082221114 @default.
- W2012637779 cites W2085343081 @default.
- W2012637779 cites W2086088161 @default.
- W2012637779 cites W2086224669 @default.
- W2012637779 cites W2090697834 @default.
- W2012637779 cites W2094018403 @default.
- W2012637779 cites W2095983586 @default.
- W2012637779 cites W2107564830 @default.
- W2012637779 cites W2108217811 @default.
- W2012637779 cites W2111074415 @default.
- W2012637779 cites W2114295422 @default.
- W2012637779 cites W2115612531 @default.
- W2012637779 cites W2135437943 @default.
- W2012637779 cites W2138406465 @default.
- W2012637779 cites W2138763689 @default.
- W2012637779 cites W2142234529 @default.
- W2012637779 cites W2154920507 @default.
- W2012637779 cites W2156667808 @default.
- W2012637779 cites W2158873726 @default.
- W2012637779 cites W2171396613 @default.
- W2012637779 cites W2171665364 @default.
- W2012637779 cites W2172020795 @default.
- W2012637779 cites W2950472625 @default.
- W2012637779 cites W2951901527 @default.
- W2012637779 cites W3021276718 @default.
- W2012637779 cites W4210963845 @default.
- W2012637779 cites W4237943893 @default.
- W2012637779 doi "https://doi.org/10.1002/adfm.201102027" @default.
- W2012637779 hasPublicationYear "2012" @default.