FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012669025> ?p ?o ?g. }

• W2012669025 endingPage "249" @default.
• W2012669025 startingPage "233" @default.
• W2012669025 abstract "In isotachophoresis (ITP), the sample constituents migrate, depending on their concentrations in the loaded sample, either in fully developed zones or in the boundary layers between the zones of constituents of the corresponding effective mobilities. The latter (spike) migration mode is analytically beneficial in selective detections of trace analytes, especially, when appropriately chosen discrete spacers minimize detection interferences due to matrix constituents. To facilitate a search for suitable mixtures of discrete spacers, a two-step calculation procedure was developed in this work. Using a pool of discrete spacers consisting of 42 anionic and zwitterionic constituents, this procedure was shown effective in the anionic ITP separations performed at pH = 6.5-10.0. Besides the predictions of the migration orders, it was helpful in identifying the spacing constituents that could cause resolution problems due to an uncertainty with which pH of the leading electrolyte solution is known. The ionic mobility and pKa data, taken for the spacing constituents from the literature and the ones obtained from the ITP experiments carried out in this work, were used in the calculations performed in a context with the choice of spacers. Although the data obtained from the ITP experiments provided better results, small uncertainties with which they were acquired (attributable to fluctuations in the experimental conditions) set practical limits in the calculation based choice of multi-component mixtures of the spacing constituents." @default.
• W2012669025 created "2016-06-24" @default.
• W2012669025 creator A5000930390 @default.
• W2012669025 creator A5053829377 @default.
• W2012669025 creator A5062625934 @default.
• W2012669025 date "2003-11-01" @default.
• W2012669025 modified "2023-10-17" @default.
• W2012669025 title "Computer-assisted choice of discrete spacers for anionic isotachophoresis separations" @default.
• W2012669025 cites W1489147104 @default.
• W2012669025 cites W1507026143 @default.
• W2012669025 cites W1525483836 @default.
• W2012669025 cites W1526363802 @default.
• W2012669025 cites W1526505950 @default.
• W2012669025 cites W1583260256 @default.
• W2012669025 cites W1590632623 @default.
• W2012669025 cites W1907152296 @default.
• W2012669025 cites W1971119842 @default.
• W2012669025 cites W1973160543 @default.
• W2012669025 cites W1975127346 @default.
• W2012669025 cites W1981605861 @default.
• W2012669025 cites W1984056959 @default.
• W2012669025 cites W1990118923 @default.
• W2012669025 cites W1991939792 @default.
• W2012669025 cites W1993504425 @default.
• W2012669025 cites W1995978433 @default.
• W2012669025 cites W2000851118 @default.
• W2012669025 cites W2001081022 @default.
• W2012669025 cites W2005677139 @default.
• W2012669025 cites W2007651735 @default.
• W2012669025 cites W2008515909 @default.
• W2012669025 cites W2009293403 @default.
• W2012669025 cites W2009811789 @default.
• W2012669025 cites W2013312445 @default.
• W2012669025 cites W2025284254 @default.
• W2012669025 cites W2026546679 @default.
• W2012669025 cites W2034959530 @default.
• W2012669025 cites W2035783776 @default.
• W2012669025 cites W2038809964 @default.
• W2012669025 cites W2039952003 @default.
• W2012669025 cites W2040421207 @default.
• W2012669025 cites W2041271251 @default.
• W2012669025 cites W2042793639 @default.
• W2012669025 cites W2046689498 @default.
• W2012669025 cites W2047946460 @default.
• W2012669025 cites W2051773080 @default.
• W2012669025 cites W2053230746 @default.
• W2012669025 cites W2056014513 @default.
• W2012669025 cites W2059330601 @default.
• W2012669025 cites W2072674835 @default.
• W2012669025 cites W2075499103 @default.
• W2012669025 cites W2078970364 @default.
• W2012669025 cites W2079131078 @default.
• W2012669025 cites W2085435986 @default.
• W2012669025 cites W2086490134 @default.
• W2012669025 cites W2086536684 @default.
• W2012669025 cites W2090363892 @default.
• W2012669025 cites W2091547000 @default.
• W2012669025 cites W2094469513 @default.
• W2012669025 cites W2102414591 @default.
• W2012669025 cites W2144395153 @default.
• W2012669025 cites W2151498549 @default.
• W2012669025 cites W2741522657 @default.
• W2012669025 cites W2949490804 @default.
• W2012669025 cites W4235503495 @default.
• W2012669025 cites W4252395097 @default.
• W2012669025 cites W4302764980 @default.
• W2012669025 cites W48561702 @default.
• W2012669025 doi "https://doi.org/10.1016/j.chroma.2003.08.030" @default.
• W2012669025 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14620574" @default.
• W2012669025 hasPublicationYear "2003" @default.
• W2012669025 type Work @default.
• W2012669025 sameAs 2012669025 @default.
• W2012669025 citedByCount "18" @default.
• W2012669025 countsByYear W20126690252012 @default.
• W2012669025 countsByYear W20126690252014 @default.
• W2012669025 countsByYear W20126690252016 @default.
• W2012669025 countsByYear W20126690252018 @default.
• W2012669025 countsByYear W20126690252020 @default.
• W2012669025 countsByYear W20126690252021 @default.
• W2012669025 countsByYear W20126690252022 @default.
• W2012669025 crossrefType "journal-article" @default.
• W2012669025 hasAuthorship W2012669025A5000930390 @default.
• W2012669025 hasAuthorship W2012669025A5053829377 @default.
• W2012669025 hasAuthorship W2012669025A5062625934 @default.
• W2012669025 hasConcept C10390740 @default.
• W2012669025 hasConcept C106487976 @default.
• W2012669025 hasConcept C113196181 @default.
• W2012669025 hasConcept C121332964 @default.
• W2012669025 hasConcept C145148216 @default.
• W2012669025 hasConcept C147789679 @default.
• W2012669025 hasConcept C151730666 @default.
• W2012669025 hasConcept C17525397 @default.
• W2012669025 hasConcept C178790620 @default.
• W2012669025 hasConcept C185592680 @default.
• W2012669025 hasConcept C186060115 @default.
• W2012669025 hasConcept C186293402 @default.
• W2012669025 hasConcept C18762648 @default.
• W2012669025 hasConcept C2182769 @default.

• next