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- W2012695168 abstract "The polymer-solvent interaction parameter x for solutions of poly(dimethylsiloxane) (PDMS) of different molecular weights (4600–220000) in methylethylketone (MEK) at segment fractions of PDMS ø2 ranging from 0.3 to 0.7 was measured by means of the vapour pressure method at 30°C, (20°C higher than the θ temperature for the PDMS-MEK system). The x values obtained experimentally were found to be almost independent of the molecular weight of PDMS. The observed x values were reproduced by applying Flory's new theory with evaluated values of three quantities: (1) the ratio of the surface area per segment for the polymer to that for the solvent s2s1; (2) the enthalpy exchange parameter X12 and (3) the entropy exchange parameter Q12." @default.
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- W2012695168 date "1982-08-01" @default.
- W2012695168 modified "2023-10-13" @default.
- W2012695168 title "Dependence of interaction parameter on molecular weight and concentration for solutions of poly(dimethylsiloxane) in methylethylketone" @default.
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- W2012695168 doi "https://doi.org/10.1016/0032-3861(82)90272-5" @default.
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