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- W2012697096 abstract "Luminescence properties of Cs2NaBiCl6 are reported. Absorption, excitation, steady and pulsed fluorescence spectra have been investigated over a wide temperature range. The temperature dependences of the integrated fluorescence intensities and lifetimes versus temperature were obtained under selective excitation in the main absorption bands. Absorption processes are described using a molecular orbital scheme. The behaviour of the absorption (intensity and splitting) with the temperature provide evidence of a strong interaction with the lattice as shown in alkali halides doped with mercury-like ions. Emission processes are discussed. The lifetime measurements do not agree with the classical three-levels scheme generally proposed for luminescent processes in Bi3+ centres. Absorption and emission results seem to support the hypothesis of a strong coupling with the vibrational modes. In addition, the behaviour of the decay times at low temperatures are consistent with migration and trapping sites effects." @default.
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- W2012697096 date "1978-06-01" @default.
- W2012697096 modified "2023-09-30" @default.
- W2012697096 title "Optical properties of Cs2NaBiCl6" @default.
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- W2012697096 doi "https://doi.org/10.1016/0022-2313(78)90026-1" @default.
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