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• W2012709454 abstract "A new general route to nitrido complexes of Cr(V) based on nitrogen-atom transfer from Mn(N)(salen) to labile CrCl3(THF)3 is presented. By this approach, the simplest nitrido complex of a first row transition metal, [Cr(N)Cl4]2-, has been synthesized and isolated. [[N(CH3)4]2[Cr(N)Cl4]·H2O crystallizes in the cubic space group Fm-3m with disordered anions. Cr−N is 1.555(19) Å, Cr−Cl is 2.2912(16) Å, and N−Cr−Cl is 101.24(4)°. The orbital splitting scheme of [Cr(N)Cl4]2- is extreme with the dx2-y2 orbital 10 000 cm-1 lower in energy than the degenerate {dzx, dyz} set of orbitals destabilized by π-bonding with the nitrido ligand. Hydrolysis of [Cr(N)Cl4]2 preserves the {Cr⋮N}2+ moiety." @default.
• W2012709454 created "2016-06-24" @default.
• W2012709454 creator A5088822503 @default.
• W2012709454 date "2003-10-09" @default.
• W2012709454 modified "2023-09-27" @default.
• W2012709454 title "[Cr(N)Cl₄]^2-: A Simple Nitrido Complex Synthesized by Nitrogen-Atom Transfer" @default.
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• W2012709454 doi "https://doi.org/10.1021/ja0371000" @default.
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