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• W2012720314 abstract "The cis -dibromination of unsaturated bicyclic bridgehead sultams 5a and 5b , and experiments designed to understand the cis -stereochemical outcome of these reactions, are described. In the case of 5b , a novel solvent dependent carbocation rearrangement occurs with the formation of 18b . cis -Dibromides 13a and 13b undergo regioselective dehydrobromination, and the participation of the resultant vinyl bromide 24a in lithiation and Pd-coupling chemistry is described. In the case of the latter, hydrogenation of the styryl products afforded a single diastereoisomer. These compounds were then studied under dissolved metal reduction conditions, in which the cleavage of both N–S and C–S bonds takes place to afford cis -2,4-diaryl-substituted pyrrolidines 35–37 ." @default.
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• W2012720314 date "2009-11-25" @default.
• W2012720314 modified "2023-10-12" @default.
• W2012720314 title "Diastereoselective functionalisation of benzo-annulated bicyclic sultams: Application for the synthesis of <i>cis</i>-2,4-diarylpyrrolidines" @default.
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• W2012720314 doi "https://doi.org/10.3762/bjoc.5.69" @default.
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