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- W2012802386 abstract "In acidic media, at pH < 7, the nitro group, in ortho-nitrobenzaldehyde (I) is reduced in a four-electron step to ortho-formylphenylhydroxylamine (II). The protonated form of II is reduced by two electrons to ortho-aminobenzaldehyde (IV), which is further reduced in a two-electron process to ortho-aminobenzylalcohol. At pH > 7, the arylhydroxylamine (II) condenses to form a nitrone, which is further reduced in two two-electron waves, corresponding to the cleavage of the N-O bond and reduction of the azomethine bond. At pH 7, formation of anthranil (III) from II is a relatively slow process: in cyclic voltammetry (CV) and d.c. polarography, II is further reduced to IV; in controlled potential electrolysis at a mercury pool electrode, the same products are obtained at 0° C, but at 25° C, III is the predominant product." @default.
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- W2012802386 date "1993-01-01" @default.
- W2012802386 modified "2023-10-13" @default.
- W2012802386 title "Polarographic and electrochemical studies of some aromatic and heterocyclic nitro compounds: Part VI. Polarographic, voltammetric, and controlled potential reduction of ortho-nitrobenzaldehyde anthranil" @default.
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- W2012802386 doi "https://doi.org/10.1002/elan.1140050110" @default.
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