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- W2012806257 abstract "The separate units which are used to construct the antibiotic obafluorin 1 in Pseudomonas fluorescens are defined by the results of D-[U-13C]glucose incorporation. A key intermediate in the biosynthesis of 1 is established to be L-p-aminophenylalanine 8; L-phenylalanine and L-p-nitrophenylalanine are very poor precursors. Results similar to those for obafluorin are obtained for p-nitrophenylacetic acid 20 which along with the derivative 4 and 2-(4-nitrophenyl)ethanol 21 are identified as new metabolites of P. fluorescens. Deuteriated samples of 20, 22 and 23 are not precursors for obafluorin 1. [2,3-3H3]-p-Aminophenylalanine 18 is incorporated into 1 with complete loss of deuterium from C-2 but retention of the deuterium present in both diastereotopic positions on C-3." @default.
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- W2012806257 date "1992-01-01" @default.
- W2012806257 modified "2023-09-25" @default.
- W2012806257 title "Biosynthesis of the antibiotic obafluorin from D-[U-13C]glucose and p-aminophenylalanine in Pseudomonas fluorescens" @default.
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- W2012806257 doi "https://doi.org/10.1039/p19920000103" @default.
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