Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012806422> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2012806422 endingPage "1149" @default.
- W2012806422 startingPage "1141" @default.
- W2012806422 abstract "An electron spin resonance (ESR) study has been made of radicals trapped in polyisobutylene irradiated at 77 K. It is concluded that only the C(Me)2CH radical remains after heat treatment above 213 K. This radical shows a very sharp doublet ESR spectrum with hyperfine splitting of about 2.2 mT. A broad doublet ESR spectrum observed without warming, which was previously assigned as C(Me)2CHis explained as a mixture of a doublet and a triplet due to the C(Me)2CH and radicals. γ-irradiation at 77 K produces these major radical components and other carbon radicals as minor species. It has also been found that a conversion of other radicals into C(Me)2CHoccurs without decay on annealing below 183 K. Heating in the range 183–213 K causes both conversion and decay of the radicals. On annealing above 213 K, only decay occurs. The ESR spectra of polyisobutylene radicals are easily saturated by microwave power even at 1.6 μW. The mechanism of radiolysis for polyisobutylene is briefly discussed." @default.
- W2012806422 created "2016-06-24" @default.
- W2012806422 creator A5007901214 @default.
- W2012806422 creator A5036086465 @default.
- W2012806422 date "1981-07-01" @default.
- W2012806422 modified "2023-10-14" @default.
- W2012806422 title "An ESR study of polyisobutylene radicals produced by γ-irradiation at 77 K" @default.
- W2012806422 doi "https://doi.org/10.1002/pol.1981.180190710" @default.
- W2012806422 hasPublicationYear "1981" @default.
- W2012806422 type Work @default.
- W2012806422 sameAs 2012806422 @default.
- W2012806422 citedByCount "15" @default.
- W2012806422 countsByYear W20128064222016 @default.
- W2012806422 countsByYear W20128064222020 @default.
- W2012806422 crossrefType "journal-article" @default.
- W2012806422 hasAuthorship W2012806422A5007901214 @default.
- W2012806422 hasAuthorship W2012806422A5036086465 @default.
- W2012806422 hasConcept C111337013 @default.
- W2012806422 hasConcept C113196181 @default.
- W2012806422 hasConcept C121332964 @default.
- W2012806422 hasConcept C1276947 @default.
- W2012806422 hasConcept C131538251 @default.
- W2012806422 hasConcept C134056017 @default.
- W2012806422 hasConcept C139066938 @default.
- W2012806422 hasConcept C159985019 @default.
- W2012806422 hasConcept C177801218 @default.
- W2012806422 hasConcept C178790620 @default.
- W2012806422 hasConcept C184779094 @default.
- W2012806422 hasConcept C185544564 @default.
- W2012806422 hasConcept C185592680 @default.
- W2012806422 hasConcept C187961010 @default.
- W2012806422 hasConcept C192562407 @default.
- W2012806422 hasConcept C2777855556 @default.
- W2012806422 hasConcept C46141821 @default.
- W2012806422 hasConcept C4839761 @default.
- W2012806422 hasConcept C66887884 @default.
- W2012806422 hasConcept C75473681 @default.
- W2012806422 hasConceptScore W2012806422C111337013 @default.
- W2012806422 hasConceptScore W2012806422C113196181 @default.
- W2012806422 hasConceptScore W2012806422C121332964 @default.
- W2012806422 hasConceptScore W2012806422C1276947 @default.
- W2012806422 hasConceptScore W2012806422C131538251 @default.
- W2012806422 hasConceptScore W2012806422C134056017 @default.
- W2012806422 hasConceptScore W2012806422C139066938 @default.
- W2012806422 hasConceptScore W2012806422C159985019 @default.
- W2012806422 hasConceptScore W2012806422C177801218 @default.
- W2012806422 hasConceptScore W2012806422C178790620 @default.
- W2012806422 hasConceptScore W2012806422C184779094 @default.
- W2012806422 hasConceptScore W2012806422C185544564 @default.
- W2012806422 hasConceptScore W2012806422C185592680 @default.
- W2012806422 hasConceptScore W2012806422C187961010 @default.
- W2012806422 hasConceptScore W2012806422C192562407 @default.
- W2012806422 hasConceptScore W2012806422C2777855556 @default.
- W2012806422 hasConceptScore W2012806422C46141821 @default.
- W2012806422 hasConceptScore W2012806422C4839761 @default.
- W2012806422 hasConceptScore W2012806422C66887884 @default.
- W2012806422 hasConceptScore W2012806422C75473681 @default.
- W2012806422 hasIssue "7" @default.
- W2012806422 hasLocation W20128064221 @default.
- W2012806422 hasOpenAccess W2012806422 @default.
- W2012806422 hasPrimaryLocation W20128064221 @default.
- W2012806422 hasRelatedWork W1966908056 @default.
- W2012806422 hasRelatedWork W1988800661 @default.
- W2012806422 hasRelatedWork W1989083680 @default.
- W2012806422 hasRelatedWork W1994394003 @default.
- W2012806422 hasRelatedWork W2012413717 @default.
- W2012806422 hasRelatedWork W2033336290 @default.
- W2012806422 hasRelatedWork W2045191548 @default.
- W2012806422 hasRelatedWork W2052213173 @default.
- W2012806422 hasRelatedWork W2118636832 @default.
- W2012806422 hasRelatedWork W2135895997 @default.
- W2012806422 hasVolume "19" @default.
- W2012806422 isParatext "false" @default.
- W2012806422 isRetracted "false" @default.
- W2012806422 magId "2012806422" @default.
- W2012806422 workType "article" @default.