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- W2012807852 abstract "Dielectric methods have been employed to study the high-pressure behavior of a polyurethane elastomer (Solithane 113) in the vicinity of its α transition. The α-loss peak is shifted to higher temperatures and broadened somewhat with the application of hydrostatic pressure up to 6.4 kbars. The slope of Tα vs. P, or dTα/dP, obtained at low frequencies was found to be equal to dTg/dP obtained by a volumetric method. Moreover, it attained a nonzero limiting value at high pressures for each frequency tested (3—30,000 Hz) and the limiting value itself increased with increasing frequency from 10.5°C/kbar at 3 Hz to 18°C/kbar at 30,000 Hz. The activation enthalpy ΔH* was found to be nearly constant over the pressure range tested, but the activation volume ΔV* decreased with increasing pressure. The relation dTα/dP = T (ΔV*/ΔH*) was shown to hold for the elastomer." @default.
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- W2012807852 date "1983-07-01" @default.
- W2012807852 modified "2023-09-23" @default.
- W2012807852 title "The dependence of dielectric response of an elastomer on hydrostatic pressure" @default.
- W2012807852 doi "https://doi.org/10.1002/pol.1983.180210718" @default.
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