FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012819296> ?p ?o ?g. }

• W2012819296 endingPage "459" @default.
• W2012819296 startingPage "451" @default.
• W2012819296 abstract "Sodium and potassium thiocyanate complex compounds of formulae [Na(hmta)(H2O)4] 2 2+ ·2SCN− (1) and [K2(hmta)(SCN)2] n (2) have been synthesized and characterised by IR spectroscopy, thermogravimetry coupled with differential thermal analysis, elemental analysis and X-ray crystallography. Each sodium and potassium cation is six co-ordinated, the sodium by one monofunctional hmta molecule, three terminal water molecules and two bridging water molecules, and the potassium by two bridging tetrafunctional hmta molecules and four bridging tetrafunctional thiocyanate ions. The coordination polyhedra of the central atoms can be described as distorted tetragonal bipyramids. The complex cations and anions of (1) are interconnected by multiple intramolecular O(water)—H···N(hmta/NCS) and O(water)—H···S hydrogen bonds to the three dimensional net. In each complex cation the intramolecular O–H···O hydrogen bonds link two terminal water molecules bonded to two metal cations. The compound (2) forms the three dimensional hybrid network in which the classical two-dimensional coordination polymers are linked by inorganic SCN− spacers to the third-dimension. Thermal analyses show that the compounds decompose gradually in three (for 1) and two (for 2) steps with formation of Na2SO4 and K2S as the final products, respectively, for 1 and 2." @default.
• W2012819296 created "2016-06-24" @default.
• W2012819296 creator A5042392769 @default.
• W2012819296 creator A5082159124 @default.
• W2012819296 creator A5091728999 @default.
• W2012819296 date "2011-10-11" @default.
• W2012819296 modified "2023-09-29" @default.
• W2012819296 title "The structure and thermal behaviour of sodium and potassium multinuclear compounds with hexamethylenetetramine" @default.
• W2012819296 cites W1628423641 @default.
• W2012819296 cites W1971208125 @default.
• W2012819296 cites W1977046172 @default.
• W2012819296 cites W1977520874 @default.
• W2012819296 cites W1980396035 @default.
• W2012819296 cites W1981554934 @default.
• W2012819296 cites W1981924276 @default.
• W2012819296 cites W1983271674 @default.
• W2012819296 cites W1989697026 @default.
• W2012819296 cites W2005436422 @default.
• W2012819296 cites W2007186644 @default.
• W2012819296 cites W2016230710 @default.
• W2012819296 cites W2026938564 @default.
• W2012819296 cites W2030231987 @default.
• W2012819296 cites W2033407526 @default.
• W2012819296 cites W2034474091 @default.
• W2012819296 cites W2034676439 @default.
• W2012819296 cites W2039313117 @default.
• W2012819296 cites W2039422209 @default.
• W2012819296 cites W2041552148 @default.
• W2012819296 cites W2048830183 @default.
• W2012819296 cites W2052893690 @default.
• W2012819296 cites W2054297336 @default.
• W2012819296 cites W2057376707 @default.
• W2012819296 cites W2057629847 @default.
• W2012819296 cites W2059650532 @default.
• W2012819296 cites W2067145967 @default.
• W2012819296 cites W2067251026 @default.
• W2012819296 cites W2078069278 @default.
• W2012819296 cites W2081670814 @default.
• W2012819296 cites W2087026767 @default.
• W2012819296 cites W2101741054 @default.
• W2012819296 cites W2120423850 @default.
• W2012819296 cites W2121904540 @default.
• W2012819296 cites W2122015041 @default.
• W2012819296 cites W2131350133 @default.
• W2012819296 cites W2137207432 @default.
• W2012819296 cites W2158744361 @default.
• W2012819296 cites W2164043498 @default.
• W2012819296 cites W2529297591 @default.
• W2012819296 cites W2952122527 @default.
• W2012819296 doi "https://doi.org/10.1007/s11224-011-9888-7" @default.
• W2012819296 hasPublicationYear "2011" @default.
• W2012819296 type Work @default.
• W2012819296 sameAs 2012819296 @default.
• W2012819296 citedByCount "12" @default.
• W2012819296 countsByYear W20128192962012 @default.
• W2012819296 countsByYear W20128192962015 @default.
• W2012819296 countsByYear W20128192962016 @default.
• W2012819296 countsByYear W20128192962019 @default.
• W2012819296 countsByYear W20128192962021 @default.
• W2012819296 countsByYear W20128192962022 @default.
• W2012819296 countsByYear W20128192962023 @default.
• W2012819296 crossrefType "journal-article" @default.
• W2012819296 hasAuthorship W2012819296A5042392769 @default.
• W2012819296 hasAuthorship W2012819296A5082159124 @default.
• W2012819296 hasAuthorship W2012819296A5091728999 @default.
• W2012819296 hasBestOaLocation W20128192961 @default.
• W2012819296 hasConcept C112887158 @default.
• W2012819296 hasConcept C115624301 @default.
• W2012819296 hasConcept C178790620 @default.
• W2012819296 hasConcept C179104552 @default.
• W2012819296 hasConcept C185592680 @default.
• W2012819296 hasConcept C2775867063 @default.
• W2012819296 hasConcept C2776294642 @default.
• W2012819296 hasConcept C2781182303 @default.
• W2012819296 hasConcept C2781432337 @default.
• W2012819296 hasConcept C32909587 @default.
• W2012819296 hasConcept C517785266 @default.
• W2012819296 hasConcept C537181965 @default.
• W2012819296 hasConcept C71240020 @default.
• W2012819296 hasConcept C75079739 @default.
• W2012819296 hasConcept C8010536 @default.
• W2012819296 hasConceptScore W2012819296C112887158 @default.
• W2012819296 hasConceptScore W2012819296C115624301 @default.
• W2012819296 hasConceptScore W2012819296C178790620 @default.
• W2012819296 hasConceptScore W2012819296C179104552 @default.
• W2012819296 hasConceptScore W2012819296C185592680 @default.
• W2012819296 hasConceptScore W2012819296C2775867063 @default.
• W2012819296 hasConceptScore W2012819296C2776294642 @default.
• W2012819296 hasConceptScore W2012819296C2781182303 @default.
• W2012819296 hasConceptScore W2012819296C2781432337 @default.
• W2012819296 hasConceptScore W2012819296C32909587 @default.
• W2012819296 hasConceptScore W2012819296C517785266 @default.
• W2012819296 hasConceptScore W2012819296C537181965 @default.
• W2012819296 hasConceptScore W2012819296C71240020 @default.
• W2012819296 hasConceptScore W2012819296C75079739 @default.
• W2012819296 hasConceptScore W2012819296C8010536 @default.
• W2012819296 hasIssue "2" @default.
• W2012819296 hasLocation W20128192961 @default.

• next