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• W2012833182 abstract "A modular synthetic approach to bidentate and tridentate imino-thioglycoside ligands is reported. In only 5 steps from the known glucosamine derivative 1, a conveniently functionalized thioglycoside 5 is obtained, which after imination afforded the desired ligands in excellent yields. The tridentate phosphine imine thioglycoside ligand 10 was found to be a highly efficient catalyst precursor for palladium-(0)-catalysed asymmetric alkylation of 1,3-diphenylpropenylacetate (8) with dimethyl malonate. The study of a Pd(II) complex shows that there is an efficient stereochemical control of the sulfur configuration upon coordination to the palladium." @default.
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• W2012833182 date "2006-06-01" @default.
• W2012833182 modified "2023-10-18" @default.
• W2012833182 title "Mixed S/N and S/P/N ligands from carbohydrates: Synthesis and application in palladium-catalyzed allylic alkylation" @default.
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• W2012833182 doi "https://doi.org/10.1016/j.ica.2006.02.001" @default.
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