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- W2012838391 abstract "The reaction of (η5-C5H5)Co(CO)2 with ClCCCl gives hexachlorobenzene in addition to at least six different products, three of which were characterized by X-ray crystallography: The first π-complex of hexachlorotropone, (CpCo)(η4-C7Cl6O), shows η4-coordination of the two non-conjugated double bonds, which has not been previously observed in other complexes having cycloheptatrienone ligands. The structure of a 1,2-dicobaltacycloheptadienone is also described for the first time. Finally, the structure of a bimetallic tetrachlorocobaltacyclopentadiene has been verified by XRD methods. Die Reaktion von (η5-C5H5)Co(CO)2 mit ClCCCl ergibt neben Hexachlorbenzol mindestens sechs verschiedene Produkte, von denen drei durch Röntgenstrukturanalyse charakterisiert werden konnten: Der erste π-Komplex von Hexachlortropon, (CpCo)(η4-C7Cl6O) weist η4-Koordination zweier nicht benachbarter Doppelbindungen auf, was bisher in anderen Komplexen mit Cycloheptatrienon-Liganden nicht beobachtet wurde. Ebenfalls zum erstenmal wird die Struktur eines 1,2-Dikobaltacycloheptadienons beschrieben. Schließlich konnte die Struktur eines bimetallischen Tetrahchlorocobaltacyclopentadienons kristallographisch bestätigt werden." @default.
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- W2012838391 date "1990-07-01" @default.
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- W2012838391 title "Komplexchemie perhalogenierter cyclopentadiene und alkine VI. Reaktion von dichlorethin mit (η5-C5H5)Co(CO)2. Strukturen von (CpCo)(η4-C7Cl6O), [CpCo]2[μ-(η1,η2)2-C5Cl4O] und [η4-(CpCl)](CoCp)" @default.
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- W2012838391 doi "https://doi.org/10.1016/0022-328x(90)80179-4" @default.
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