FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012871574> ?p ?o ?g. }

• W2012871574 endingPage "2623" @default.
• W2012871574 startingPage "2616" @default.
• W2012871574 abstract "A new tridentate ligand [(2-hydroxybenzyl)(2-(imidazol-2-yl)ethyl)]amine (HBHA) and its first dinuclear FeIII complex have been synthesized. The crystal structures of HBHA and of the complex [Fe2III(BHA)2(μ-OCH3)2(μ-OAc)](ClO4) (1) have been solved by X-ray crystallography. In the cation of complex 1, each BHA− anion is arranged in a facial mode while one acetate and two methoxo groups as bridging ligands complete the coordination spheres of the FeIII centres. The FeIII ions are weakly antiferromagnetically coupled (J = −10.1 cm−1) and undergo a quasi-reversible one-electron redox process attributed to the Fe2III/FeIIFeIII couple. Complex 1 also displays an intense phenolate-to-FeIII charge transfer transition at 517 nm (ε = 5560 dm3 mol−1 cm−1/Fe2III). The Mössbauer spectrum of 1 at 115 K shows only one quadrupole doublet, with δ = 0.47 and ΔEQ = 0.80 mm s−1. A comparison of the structural, magnetic and spectroscopic properties of 1 and those detected in the Fe2III form of purple acid phosphatases suggests that this compound is a potential structural model for the active site of these metalloenzymes. In addition, complex 1 also mimics some structural features found in methane monooxygenase." @default.
• W2012871574 created "2016-06-24" @default.
• W2012871574 creator A5010008684 @default.
• W2012871574 creator A5046209650 @default.
• W2012871574 creator A5047335974 @default.
• W2012871574 creator A5049195832 @default.
• W2012871574 creator A5056370623 @default.
• W2012871574 creator A5089175587 @default.
• W2012871574 creator A5089320282 @default.
• W2012871574 date "2001-01-01" @default.
• W2012871574 modified "2023-10-03" @default.
• W2012871574 title "A new FeIII(µ-OCH3)2(µ-OAc)FeIII complex containing phenolate and imidazole ligands as a structural model for the active site of non-heme diiron enzymes†" @default.
• W2012871574 cites W121022101 @default.
• W2012871574 cites W1515122089 @default.
• W2012871574 cites W1582923620 @default.
• W2012871574 cites W1963821971 @default.
• W2012871574 cites W1964893634 @default.
• W2012871574 cites W1967244854 @default.
• W2012871574 cites W1968592306 @default.
• W2012871574 cites W1979896323 @default.
• W2012871574 cites W1982067906 @default.
• W2012871574 cites W1985000707 @default.
• W2012871574 cites W1991994013 @default.
• W2012871574 cites W2003221148 @default.
• W2012871574 cites W2004303185 @default.
• W2012871574 cites W2006128611 @default.
• W2012871574 cites W2016097286 @default.
• W2012871574 cites W2020386376 @default.
• W2012871574 cites W2021770929 @default.
• W2012871574 cites W2024461057 @default.
• W2012871574 cites W2024550232 @default.
• W2012871574 cites W2027518119 @default.
• W2012871574 cites W2031900710 @default.
• W2012871574 cites W2035401638 @default.
• W2012871574 cites W2036342654 @default.
• W2012871574 cites W2037253356 @default.
• W2012871574 cites W2040462313 @default.
• W2012871574 cites W2040687623 @default.
• W2012871574 cites W2049024956 @default.
• W2012871574 cites W2051359785 @default.
• W2012871574 cites W2062258949 @default.
• W2012871574 cites W2067601423 @default.
• W2012871574 cites W2068023207 @default.
• W2012871574 cites W2081298460 @default.
• W2012871574 cites W2081312328 @default.
• W2012871574 cites W2090339502 @default.
• W2012871574 cites W2091897331 @default.
• W2012871574 doi "https://doi.org/10.1039/b100913n" @default.
• W2012871574 hasPublicationYear "2001" @default.
• W2012871574 type Work @default.
• W2012871574 sameAs 2012871574 @default.
• W2012871574 citedByCount "39" @default.
• W2012871574 countsByYear W20128715742014 @default.
• W2012871574 countsByYear W20128715742015 @default.
• W2012871574 countsByYear W20128715742018 @default.
• W2012871574 countsByYear W20128715742020 @default.
• W2012871574 countsByYear W20128715742022 @default.
• W2012871574 countsByYear W20128715742023 @default.
• W2012871574 crossrefType "journal-article" @default.
• W2012871574 hasAuthorship W2012871574A5010008684 @default.
• W2012871574 hasAuthorship W2012871574A5046209650 @default.
• W2012871574 hasAuthorship W2012871574A5047335974 @default.
• W2012871574 hasAuthorship W2012871574A5049195832 @default.
• W2012871574 hasAuthorship W2012871574A5056370623 @default.
• W2012871574 hasAuthorship W2012871574A5089175587 @default.
• W2012871574 hasAuthorship W2012871574A5089320282 @default.
• W2012871574 hasConcept C115624301 @default.
• W2012871574 hasConcept C116569031 @default.
• W2012871574 hasConcept C131779359 @default.
• W2012871574 hasConcept C145148216 @default.
• W2012871574 hasConcept C170493617 @default.
• W2012871574 hasConcept C178790620 @default.
• W2012871574 hasConcept C179104552 @default.
• W2012871574 hasConcept C181199279 @default.
• W2012871574 hasConcept C185592680 @default.
• W2012871574 hasConcept C23296010 @default.
• W2012871574 hasConcept C2780874372 @default.
• W2012871574 hasConcept C41183919 @default.
• W2012871574 hasConcept C55493867 @default.
• W2012871574 hasConcept C55904794 @default.
• W2012871574 hasConcept C71240020 @default.
• W2012871574 hasConcept C8010536 @default.
• W2012871574 hasConceptScore W2012871574C115624301 @default.
• W2012871574 hasConceptScore W2012871574C116569031 @default.
• W2012871574 hasConceptScore W2012871574C131779359 @default.
• W2012871574 hasConceptScore W2012871574C145148216 @default.
• W2012871574 hasConceptScore W2012871574C170493617 @default.
• W2012871574 hasConceptScore W2012871574C178790620 @default.
• W2012871574 hasConceptScore W2012871574C179104552 @default.
• W2012871574 hasConceptScore W2012871574C181199279 @default.
• W2012871574 hasConceptScore W2012871574C185592680 @default.
• W2012871574 hasConceptScore W2012871574C23296010 @default.
• W2012871574 hasConceptScore W2012871574C2780874372 @default.
• W2012871574 hasConceptScore W2012871574C41183919 @default.
• W2012871574 hasConceptScore W2012871574C55493867 @default.
• W2012871574 hasConceptScore W2012871574C55904794 @default.
• W2012871574 hasConceptScore W2012871574C71240020 @default.
• W2012871574 hasConceptScore W2012871574C8010536 @default.

• next