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- W2012875650 abstract "The temperature and pressure dependence of the rate coefficient for the reaction of iodine monoxide radicals with dimethyl sulfide (DMS), IO + DMS → I + DMSO (1), was studied using laser induced fluorescence (LIF) to monitor the temporal profile of IO following 351 nm photolysis of RI/DMS/NO2/He (RI = CH3I/CF3I) mixtures. The study was performed over the range T = 296–468 K yielding a positive activation energy and k1 = (9.6 ± 8.8) × 10−12 exp{−(1816 ± 397)/T}. No dependence was observed on total pressure between 5–300 Torr. The rate coefficient at 296 K was determined as (2.0 ± 0.40.6) × 10−14 cm3 molecule−1 s−1, more than an order of magnitude smaller than a recent study but in reasonable agreement with the previous literature." @default.
- W2012875650 created "2016-06-24" @default.
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- W2012875650 date "2005-01-01" @default.
- W2012875650 modified "2023-10-18" @default.
- W2012875650 title "Kinetics study of the reaction of iodine monoxide radicals with dimethyl sulfide" @default.
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- W2012875650 doi "https://doi.org/10.1039/b502989a" @default.
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