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- W2012877046 abstract "The first example of preparation of 6-(β-d-mannopyranosylamino)-9H-purine (8), whose N-glycosidic linkage corresponds to a natural antibiotic, spicamycin, by Pd-catalyzed coupling reaction of a mannopyranosylamine with 9-protected-6-chloropurine, followed by deprotection, is described. Its β-d-gluco isomer (11) was also synthesized. This work established the procedure to construct the novel N-glycoside, in which the pyranose unit is connected to the amino group at C(6) of adenine moiety." @default.
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- W2012877046 date "1999-03-01" @default.
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- W2012877046 title "Pd-Catalyzed coupling reaction of glycosylamines with 6-chloropurines: Synthesis of 6-(β-d-mannopyranosylamino)-9H-purine and its β-d-gluco isomer, N-glycoside models for spicamycin and septacidin" @default.
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- W2012877046 doi "https://doi.org/10.1016/s0040-4039(99)00250-6" @default.
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