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- W2012883670 abstract "It has been demonstrated that the equilibrium state of Al deposited on Pd (0 0 1) and annealed to 900 K is a (2 × 2)p4g structure induced by the stress related to the formation of a pure Pd surface layer over a c(2 × 2) Al–Pd second layer. This state can be changed by exposure to oxygen (at room temperature) which causes the Al to migrate to the surface layer with a concentration of up to 50% as measured by non-thermal removal of oxygen. In this process the surface is exposed to H2 at 375 K and the oxygen is removed. The oxygen-covered surface assumes a (1 × 1) structure. Once this surface is annealed to 700 K the oxygen is desorbed. Annealing to higher temperatures (900 K) returns the surface to the initial (2 × 2)p4g structure. This cycle has been followed for five cycles without significant loss of Al demonstrating the trapping power of the second layer structure." @default.
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- W2012883670 date "1998-02-01" @default.
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- W2012883670 title "Equilibrium and non-equilibrium surface structures of Al/Pd(001)" @default.
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