Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012887512> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2012887512 endingPage "7" @default.
- W2012887512 startingPage "1" @default.
- W2012887512 abstract "For hydrogen transfer reactions with moderate degrees of tunneling, the semiclassical relationship of deuterium, tritium to protium, tritium isotope effects is predicted to break down, such that (kDkT)3.26 < kHkT. By contrast, kinetically complex reactions produce (kDkT)3.26 > kHkT. We now show that these limiting cases may not pertain under the conditions of (i) measured secondary kinetic isotope effects which fall below their equilibrium limits and (ii) extensive hydrogen tunneling. Although condition (i) could lead to a false signature of tunneling, ambiguities of interpretation can be avoided by the simultaneous measurement of exponential relationships for primary and secondary isotope effects. With the exception of reactions where the H-transfer process is known to be fully rate determining, condition (ii) may lead to an underestimate of quantum effects as judged by exponential relationships." @default.
- W2012887512 created "2016-06-24" @default.
- W2012887512 creator A5043903400 @default.
- W2012887512 creator A5066409965 @default.
- W2012887512 date "1992-03-01" @default.
- W2012887512 modified "2023-10-11" @default.
- W2012887512 title "Exponential relationships among multiple hydrogen isotope effects as probes of hydrogen tunneling" @default.
- W2012887512 cites W1988373345 @default.
- W2012887512 cites W1995870328 @default.
- W2012887512 cites W2020355830 @default.
- W2012887512 cites W2043634337 @default.
- W2012887512 cites W2046562899 @default.
- W2012887512 cites W2064193868 @default.
- W2012887512 cites W2076299995 @default.
- W2012887512 cites W2084119857 @default.
- W2012887512 cites W2087123471 @default.
- W2012887512 cites W2096555896 @default.
- W2012887512 cites W73824665 @default.
- W2012887512 doi "https://doi.org/10.1016/0045-2068(92)90021-t" @default.
- W2012887512 hasPublicationYear "1992" @default.
- W2012887512 type Work @default.
- W2012887512 sameAs 2012887512 @default.
- W2012887512 citedByCount "26" @default.
- W2012887512 crossrefType "journal-article" @default.
- W2012887512 hasAuthorship W2012887512A5043903400 @default.
- W2012887512 hasAuthorship W2012887512A5066409965 @default.
- W2012887512 hasConcept C120398109 @default.
- W2012887512 hasConcept C121332964 @default.
- W2012887512 hasConcept C127413603 @default.
- W2012887512 hasConcept C134306372 @default.
- W2012887512 hasConcept C135889238 @default.
- W2012887512 hasConcept C147597530 @default.
- W2012887512 hasConcept C151376022 @default.
- W2012887512 hasConcept C159467904 @default.
- W2012887512 hasConcept C164304813 @default.
- W2012887512 hasConcept C178790620 @default.
- W2012887512 hasConcept C184779094 @default.
- W2012887512 hasConcept C185592680 @default.
- W2012887512 hasConcept C188198153 @default.
- W2012887512 hasConcept C2776640939 @default.
- W2012887512 hasConcept C2780263894 @default.
- W2012887512 hasConcept C33923547 @default.
- W2012887512 hasConcept C512968161 @default.
- W2012887512 hasConcept C535169671 @default.
- W2012887512 hasConcept C58364064 @default.
- W2012887512 hasConcept C62520636 @default.
- W2012887512 hasConcept C62538594 @default.
- W2012887512 hasConcept C69928629 @default.
- W2012887512 hasConcept C78519656 @default.
- W2012887512 hasConcept C84114770 @default.
- W2012887512 hasConceptScore W2012887512C120398109 @default.
- W2012887512 hasConceptScore W2012887512C121332964 @default.
- W2012887512 hasConceptScore W2012887512C127413603 @default.
- W2012887512 hasConceptScore W2012887512C134306372 @default.
- W2012887512 hasConceptScore W2012887512C135889238 @default.
- W2012887512 hasConceptScore W2012887512C147597530 @default.
- W2012887512 hasConceptScore W2012887512C151376022 @default.
- W2012887512 hasConceptScore W2012887512C159467904 @default.
- W2012887512 hasConceptScore W2012887512C164304813 @default.
- W2012887512 hasConceptScore W2012887512C178790620 @default.
- W2012887512 hasConceptScore W2012887512C184779094 @default.
- W2012887512 hasConceptScore W2012887512C185592680 @default.
- W2012887512 hasConceptScore W2012887512C188198153 @default.
- W2012887512 hasConceptScore W2012887512C2776640939 @default.
- W2012887512 hasConceptScore W2012887512C2780263894 @default.
- W2012887512 hasConceptScore W2012887512C33923547 @default.
- W2012887512 hasConceptScore W2012887512C512968161 @default.
- W2012887512 hasConceptScore W2012887512C535169671 @default.
- W2012887512 hasConceptScore W2012887512C58364064 @default.
- W2012887512 hasConceptScore W2012887512C62520636 @default.
- W2012887512 hasConceptScore W2012887512C62538594 @default.
- W2012887512 hasConceptScore W2012887512C69928629 @default.
- W2012887512 hasConceptScore W2012887512C78519656 @default.
- W2012887512 hasConceptScore W2012887512C84114770 @default.
- W2012887512 hasIssue "1" @default.
- W2012887512 hasLocation W20128875121 @default.
- W2012887512 hasOpenAccess W2012887512 @default.
- W2012887512 hasPrimaryLocation W20128875121 @default.
- W2012887512 hasRelatedWork W1504075764 @default.
- W2012887512 hasRelatedWork W1518029896 @default.
- W2012887512 hasRelatedWork W1848696798 @default.
- W2012887512 hasRelatedWork W1999436281 @default.
- W2012887512 hasRelatedWork W2009539630 @default.
- W2012887512 hasRelatedWork W2012647383 @default.
- W2012887512 hasRelatedWork W2077457377 @default.
- W2012887512 hasRelatedWork W2088353999 @default.
- W2012887512 hasRelatedWork W2096555896 @default.
- W2012887512 hasRelatedWork W2140075753 @default.
- W2012887512 hasVolume "20" @default.
- W2012887512 isParatext "false" @default.
- W2012887512 isRetracted "false" @default.
- W2012887512 magId "2012887512" @default.
- W2012887512 workType "article" @default.