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- W2012892095 abstract "Commercially available catalysts (SIMes)(PCy3)Cl2Ru(CHPh) (2) and (SIMes)Cl2Ru(CH-o-O-i-PrC6H4) (3) (SIMes = 1,3-dimesitylimidazolin-2-ylidene) were found to display reversible Ru oxidations via a series of electrochemical measurements. The redox processes enabled the catalysts to be switched between two different states of activity in ring opening metathesis polymerizations and ring closing metathesis reactions, primarily through changes in catalyst solubility. Moreover, treating a solution of 2 dissolved in C6H6/CH2Cl2/[1-butyl-3-methylimidazolium][PF6] (6:1:1.1 v/v/v) with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone was found to remove >99.9% of the catalyst, as determined by UV/vis spectroscopy. The methodology described herein establishes a new approach for controlling the activities displayed by commercially available olefin metathesis catalysts and for removing residual Ru species using redox-driven processes." @default.
- W2012892095 created "2016-06-24" @default.
- W2012892095 creator A5033336644 @default.
- W2012892095 creator A5059825142 @default.
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- W2012892095 date "2013-11-01" @default.
- W2012892095 modified "2023-10-03" @default.
- W2012892095 title "Metal-centered oxidations facilitate the removal of ruthenium-based olefin metathesis catalysts" @default.
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- W2012892095 doi "https://doi.org/10.1016/j.jorganchem.2013.07.063" @default.
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