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• W2012912347 abstract "Abstract An effective resistance of solid acid/phosphate composites was reduced by fabricating their thin-film electrolyte membranes for fuel cells operating at 100–300 °C. Solid acid and phosphate serve as an ionic conductor and supporting matrix, respectively, in these composites. Three-types of porous matrices were synthesized on a Pd film substrate by the electrostatic spray deposition technique, and then the solid acid was soaked under reduced pressure. The thin-film composite electrolytes showed almost the same conductivity in a wide temperature range of 100–200 °C, regardless of the difference in matrix microstructure. Above 200 °C, however, the microstructure of matrix significantly affected the thermal stability of the thin-film composite. The composite consisting of the matrix with the reticular structure, characterized by a three-dimensional interconnected porous network, achieved high thermal stability as well as low area specific resistance. Fuel cells employing thin-film membrane electrode assemblies were successfully operated at 200 °C, and the electrochemical measurements clarified the improvements." @default.
• W2012912347 created "2016-06-24" @default.
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• W2012912347 date "2011-11-01" @default.
• W2012912347 modified "2023-09-24" @default.
• W2012912347 title "Intermediate-temperature fuel cell employing thin-film solid acid/phosphate composite electrolyte fabricated by electrostatic spray deposition" @default.
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• W2012912347 doi "https://doi.org/10.1016/j.jpowsour.2011.07.004" @default.
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