FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012912667> ?p ?o ?g. }

• W2012912667 endingPage "7989" @default.
• W2012912667 startingPage "7978" @default.
• W2012912667 abstract "The synthesis of the potentially heptadentate ligand tris[6-((2-N,N-diethylcarbamoyl)pyridyl)methyl]amine, tpaam, containing three pyridinecarboxamide arms connected to a central nitrogen is described. Lanthanide complexes of this ligand are prepared and characterized. The crystallographic structure of the complexes of three lanthanide ions (La, Nd, Lu) is determined. The lanthanide(III) complexes of tpaam crystallize as monomeric species (in the presence of chloride or iodide counterions) in which the ligand tpaam acts as a N4O3 donor. The crystal structures presented here show that the Ln[bond]O and Ln[bond]N(pyridyl) distances in the complexes of tpaam are similar to those found for the tpaa complexes (H(3)tpaa = alpha,alpha',alpha' '-nitrilotri(6-methyl-2-pyridinecarboxylic acid) despite the difference in charge. A lengthening of the Ln[bond]N(apical) distance is observed in the tpaam complexes compared to the tpa (tris[(2-pyridyl)methyl]amine) complexes which is more marked for larger lanthanides than for smaller ones. The solution structures of the tpaam complexes were analyzed across the 4f series and compared to the solution structures of the lanthanide complexes of the tetradentate ligand tpa. Proton NMR studies are in agreement with the presence of C(3)(v) symmetric solution species for both ligands. For the larger lanthanides, the cation moves away from the apical nitrogen compared to the position occupied in tpa complexes, whereas for the smaller lanthanides, the metal ion is located in a similar position for the two ligands. Quite surprisingly, the formation constant of the Eu(tpaam)Cl(3) complex in D(2)O at 298 K (log beta(110) = 2.34(4)) is very similar to the one reported for Eu(tpa)Cl(3) (log beta(110) = 2.49(4) at 298 K in D(2)O) indicating that the addition of three amide groups to the ligand tpa does not lead to any increase in stability of the lanthanide complexes of tpaam compared to those of tpa." @default.
• W2012912667 created "2016-06-24" @default.
• W2012912667 creator A5014170261 @default.
• W2012912667 creator A5023111046 @default.
• W2012912667 creator A5035486908 @default.
• W2012912667 creator A5038597762 @default.
• W2012912667 creator A5051819146 @default.
• W2012912667 creator A5061964230 @default.
• W2012912667 creator A5082950097 @default.
• W2012912667 date "2003-10-28" @default.
• W2012912667 modified "2023-09-25" @default.
• W2012912667 title "Solid-State and Solution Properties of Cationic Lanthanide Complexes of a New Neutral Heptadentate N4O3 Tripodal Ligand" @default.
• W2012912667 cites W1967832874 @default.
• W2012912667 cites W1972102830 @default.
• W2012912667 cites W1985887955 @default.
• W2012912667 cites W1991971348 @default.
• W2012912667 cites W1997140939 @default.
• W2012912667 cites W1998722626 @default.
• W2012912667 cites W2008782359 @default.
• W2012912667 cites W2013736302 @default.
• W2012912667 cites W2014815677 @default.
• W2012912667 cites W2033503179 @default.
• W2012912667 cites W2034056900 @default.
• W2012912667 cites W2035885915 @default.
• W2012912667 cites W2053691477 @default.
• W2012912667 cites W2058817802 @default.
• W2012912667 cites W2059930216 @default.
• W2012912667 cites W2067092236 @default.
• W2012912667 cites W2068165777 @default.
• W2012912667 cites W2070598488 @default.
• W2012912667 cites W2074380115 @default.
• W2012912667 cites W2075159368 @default.
• W2012912667 cites W2082797178 @default.
• W2012912667 cites W2085265644 @default.
• W2012912667 cites W2087633444 @default.
• W2012912667 cites W2091018672 @default.
• W2012912667 cites W2099021383 @default.
• W2012912667 cites W2117435889 @default.
• W2012912667 cites W2148672374 @default.
• W2012912667 cites W2167590372 @default.
• W2012912667 cites W2169715159 @default.
• W2012912667 cites W2177595288 @default.
• W2012912667 cites W2951280957 @default.
• W2012912667 doi "https://doi.org/10.1021/ic034692e" @default.
• W2012912667 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14632516" @default.
• W2012912667 hasPublicationYear "2003" @default.
• W2012912667 type Work @default.
• W2012912667 sameAs 2012912667 @default.
• W2012912667 citedByCount "13" @default.
• W2012912667 countsByYear W20129126672014 @default.
• W2012912667 countsByYear W20129126672017 @default.
• W2012912667 countsByYear W20129126672019 @default.
• W2012912667 countsByYear W20129126672021 @default.
• W2012912667 crossrefType "journal-article" @default.
• W2012912667 hasAuthorship W2012912667A5014170261 @default.
• W2012912667 hasAuthorship W2012912667A5023111046 @default.
• W2012912667 hasAuthorship W2012912667A5035486908 @default.
• W2012912667 hasAuthorship W2012912667A5038597762 @default.
• W2012912667 hasAuthorship W2012912667A5051819146 @default.
• W2012912667 hasAuthorship W2012912667A5061964230 @default.
• W2012912667 hasAuthorship W2012912667A5082950097 @default.
• W2012912667 hasConcept C115624301 @default.
• W2012912667 hasConcept C116569031 @default.
• W2012912667 hasConcept C131779359 @default.
• W2012912667 hasConcept C145148216 @default.
• W2012912667 hasConcept C170493617 @default.
• W2012912667 hasConcept C178790620 @default.
• W2012912667 hasConcept C183882617 @default.
• W2012912667 hasConcept C185592680 @default.
• W2012912667 hasConcept C188027245 @default.
• W2012912667 hasConcept C201770740 @default.
• W2012912667 hasConcept C2779868791 @default.
• W2012912667 hasConcept C34814092 @default.
• W2012912667 hasConcept C55493867 @default.
• W2012912667 hasConcept C71240020 @default.
• W2012912667 hasConcept C8010536 @default.
• W2012912667 hasConceptScore W2012912667C115624301 @default.
• W2012912667 hasConceptScore W2012912667C116569031 @default.
• W2012912667 hasConceptScore W2012912667C131779359 @default.
• W2012912667 hasConceptScore W2012912667C145148216 @default.
• W2012912667 hasConceptScore W2012912667C170493617 @default.
• W2012912667 hasConceptScore W2012912667C178790620 @default.
• W2012912667 hasConceptScore W2012912667C183882617 @default.
• W2012912667 hasConceptScore W2012912667C185592680 @default.
• W2012912667 hasConceptScore W2012912667C188027245 @default.
• W2012912667 hasConceptScore W2012912667C201770740 @default.
• W2012912667 hasConceptScore W2012912667C2779868791 @default.
• W2012912667 hasConceptScore W2012912667C34814092 @default.
• W2012912667 hasConceptScore W2012912667C55493867 @default.
• W2012912667 hasConceptScore W2012912667C71240020 @default.
• W2012912667 hasConceptScore W2012912667C8010536 @default.
• W2012912667 hasIssue "24" @default.
• W2012912667 hasLocation W20129126671 @default.
• W2012912667 hasLocation W20129126672 @default.
• W2012912667 hasOpenAccess W2012912667 @default.
• W2012912667 hasPrimaryLocation W20129126671 @default.
• W2012912667 hasRelatedWork W1980506588 @default.
• W2012912667 hasRelatedWork W1999047717 @default.

• next