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- W2012954562 abstract "Assemblies between pseudo-enantiomers with different d8 metal centers, Δ-[M(bpy){Co(aet)2(R-pn)}]3+ (M = Pd or Pt, bpy = 2,2′-bipyridine, aet = 2-aminoethanethiolate, pn = 1,2-propanediamine), and Λ-[M′(bpy){Co(aet)2(S-pn)}]3+ (M′ ≠ M, M′ = Pd or Pt), have been examined from stereo- and spectrochemical aspects. A mixture of equimolar amounts of the optically active sulfur-bridged dinuclear complex, Δ-[M(bpy){Co(aet)2(R-pn)}](NO3)3·7H2O, and its pseudo-enantiomer, Λ-[M′(bpy){Co(aet)2(S-pn)}](NO3)3·7H2O, in H2O crystallizes as [M(bpy){Co(aet)2(R-pn)}][M′(bpy){Co(aet)2(S-pn)}](NO3)6·4H2O, in which two complex cations with imperfect enantiomorphisms form a 1 : 1 π–π stacked unit." @default.
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- W2012954562 date "2014-05-03" @default.
- W2012954562 modified "2023-09-24" @default.
- W2012954562 title "Stereospecific π–π stacking interactions between pseudo-enantiomeric sulfur-bridged dinuclear Co(III)–Pd(II) and Co(III)–Pt(II) complexes with optically active propanediamines" @default.
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- W2012954562 doi "https://doi.org/10.1080/00958972.2014.919387" @default.
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