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- W2012964507 abstract "A selective substitution of Mn 2+ centers for different cations has been attempted in CuAlS 2 powder samples. From the theoretical curve fittings of the extended X-ray absorption fine structure oscillations, it has been confirmed that most Mn is incorporated as divalent into one site of Cu or Al, as intended. The Mn 2+ centers substituted for Cu show an orange photoluminescence with a peak wavelength of 600 nm. This orange emission has a single exponential decay curve with a decay constant of 1.0 ms. By contrast, the Mn 2+ centers substituted for Al show a red emission peaking at 640 nm and have a nonexponential decay curve with a decay constant of 100 µs. This fast emission is thought to be due to the intrinsic luminescence of the 3d 5 –3d 5 transition in Mn 2+ centers occupying the Al site. The currently obtained external quantum efficiency is about 40% under 360 nm excitation at room temperature." @default.
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- W2012964507 date "2011-10-01" @default.
- W2012964507 modified "2023-10-18" @default.
- W2012964507 title "Photoluminescent Characteristics of Mn<sup>2+</sup> Centers Selectively Substituted for Different Cations in CuAlS<sub>2</sub>" @default.
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- W2012964507 doi "https://doi.org/10.1143/jjap.50.102401" @default.
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