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• W2013012922 endingPage "9359" @default.
• W2013012922 startingPage "9356" @default.
• W2013012922 abstract "The ketimide anion R2CN− is an important class of chemically robust ligand that binds strongly to metal ions and is considered ideal for supporting reactive metal fragments due to its inert spectator nature; this contrasts with R2N− amides that exhibit a wide range of reactivities. Here, we report the synthesis and characterization of a rare example of an actinide ketimide complex [Th(BIPMTMS){N(SiMe3)2}(NCPh2)] [2, BIPMTMS=C(PPh2NSiMe3)2]. Complex 2 contains ThCcarbene, ThNamide and ThNketimide linkages, thereby presenting the opportunity to probe the preferential reactivity of these linkages. Importantly, reactivity studies of 2 with unsaturated substrates shows that insertion reactions occur preferentially at the ThNketimide bond rather than at the ThCcarbene or ThNamide bonds. This overturns the established view that metal-ketimide linkages are purely inert spectators." @default.
• W2013012922 created "2016-06-24" @default.
• W2013012922 creator A5015509328 @default.
• W2013012922 creator A5082680062 @default.
• W2013012922 creator A5084750854 @default.
• W2013012922 creator A5086963679 @default.
• W2013012922 date "2014-07-07" @default.
• W2013012922 modified "2023-10-12" @default.
• W2013012922 title "The Ketimide Ligand is Not Just an Inert Spectator: Heteroallene Insertion Reactivity of an Actinide-Ketimide Linkage in a Thorium Carbene Amide Ketimide Complex" @default.
• W2013012922 cites W1965572555 @default.
• W2013012922 cites W1968222522 @default.
• W2013012922 cites W1969524939 @default.
• W2013012922 cites W1970011234 @default.
• W2013012922 cites W1971386814 @default.
• W2013012922 cites W1973910466 @default.
• W2013012922 cites W1974425403 @default.
• W2013012922 cites W1976169026 @default.
• W2013012922 cites W1978188241 @default.
• W2013012922 cites W1984178497 @default.
• W2013012922 cites W1990853648 @default.
• W2013012922 cites W1994367898 @default.
• W2013012922 cites W1998731725 @default.
• W2013012922 cites W1999487859 @default.
• W2013012922 cites W2001815210 @default.
• W2013012922 cites W2003063429 @default.
• W2013012922 cites W2003689577 @default.
• W2013012922 cites W2007302041 @default.
• W2013012922 cites W2009338237 @default.
• W2013012922 cites W2011044004 @default.
• W2013012922 cites W2012698172 @default.
• W2013012922 cites W2012940626 @default.
• W2013012922 cites W2019176142 @default.
• W2013012922 cites W2020042764 @default.
• W2013012922 cites W2020279342 @default.
• W2013012922 cites W2024838114 @default.
• W2013012922 cites W2024863575 @default.
• W2013012922 cites W2029727253 @default.
• W2013012922 cites W2032581014 @default.
• W2013012922 cites W2042483575 @default.
• W2013012922 cites W2045247507 @default.
• W2013012922 cites W2045903488 @default.
• W2013012922 cites W2050326270 @default.
• W2013012922 cites W2051923010 @default.
• W2013012922 cites W2052530292 @default.
• W2013012922 cites W2056056214 @default.
• W2013012922 cites W2061128926 @default.
• W2013012922 cites W2065169748 @default.
• W2013012922 cites W2065982719 @default.
• W2013012922 cites W2069624363 @default.
• W2013012922 cites W2070738837 @default.
• W2013012922 cites W2078186933 @default.
• W2013012922 cites W2081180644 @default.
• W2013012922 cites W2082545887 @default.
• W2013012922 cites W2092072692 @default.
• W2013012922 cites W2094506153 @default.
• W2013012922 cites W2096735985 @default.
• W2013012922 cites W2101899438 @default.
• W2013012922 cites W2107473053 @default.
• W2013012922 cites W2114737710 @default.
• W2013012922 cites W2118126257 @default.
• W2013012922 cites W2121910298 @default.
• W2013012922 cites W2123715208 @default.
• W2013012922 cites W2132994740 @default.
• W2013012922 cites W2153142143 @default.
• W2013012922 cites W2153569398 @default.
• W2013012922 cites W2157080717 @default.
• W2013012922 cites W2158621087 @default.
• W2013012922 cites W2159098862 @default.
• W2013012922 cites W2170986117 @default.
• W2013012922 cites W2312681809 @default.
• W2013012922 cites W2314129795 @default.
• W2013012922 cites W2316958242 @default.
• W2013012922 cites W2319510546 @default.
• W2013012922 cites W2319796473 @default.
• W2013012922 cites W2320715933 @default.
• W2013012922 cites W2324100400 @default.
• W2013012922 cites W2326915061 @default.
• W2013012922 cites W2327193991 @default.
• W2013012922 cites W2328072234 @default.
• W2013012922 cites W2330106373 @default.
• W2013012922 cites W2330819282 @default.
• W2013012922 cites W2331758557 @default.
• W2013012922 cites W2332019390 @default.
• W2013012922 cites W2334053105 @default.
• W2013012922 cites W2949457268 @default.
• W2013012922 cites W3004598420 @default.
• W2013012922 cites W4233302586 @default.
• W2013012922 cites W4236553230 @default.
• W2013012922 cites W4247984921 @default.
• W2013012922 cites W4248390630 @default.
• W2013012922 cites W4249165426 @default.
• W2013012922 cites W4250118731 @default.
• W2013012922 cites W4253984266 @default.
• W2013012922 doi "https://doi.org/10.1002/anie.201404898" @default.
• W2013012922 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4464536" @default.
• W2013012922 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25044515" @default.
• W2013012922 hasPublicationYear "2014" @default.
• W2013012922 type Work @default.

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