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• W2013015710 abstract "The TbBaCo1.92Fe0.08O5+δ layered perovskite, exhibiting a metal–insulator phase transition at TMI ∼ 340 K, has been investigated by the Mössbauer spectroscopy method. It was found that the Fe3+ ions have two different positions in the low-temperature insulator phase (at T < TMI) and predominantly one position in the high-temperature metallic region above TMI. X-ray diffraction experiments have revealed an orthorhombic-to-tetragonal crystal structure transformation taking place at TMI. These results have been interpreted as favouring an oxygen vacancy order–disorder transition that occurs simultaneously with the metal–insulator one." @default.
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• W2013015710 date "2002-09-20" @default.
• W2013015710 modified "2023-10-13" @default.
• W2013015710 title "Instability of oxygen vacancy ordering at the metal insulator transition in the iron-doped TbBaCo₂O_5.5layered perovskite" @default.
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• W2013015710 doi "https://doi.org/10.1088/0953-8984/14/39/310" @default.
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