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- W2013025746 abstract "The reaction of [N(PPh3)2]2[Pt2(µ-X)2(C6F5)4](X = Cl, Br or I) with bis(diphenylphosphino)methane (dppm) at room temperature in CH2Cl2 affords [N(PPh3)2]2[(C6F5)2XPt(µ-dppm)PtX(C6F5)2](X = Cl 1, Br 2 or I 3) in good yield as the kinetic products. Further reactions between 1–3 and AgClO4(molar ratio 1 : 1) in acetone–tetrahydrofuran render the corresponding derivatives [N(PPh3)2][(C6F5)2Pt(µ-X)(µ-ddppm)Pt(C6F5)2][X = Cl, Br or I) and AgX. These complexes are very stable, and the bridging system is not cleaved by anionic (X–) or neutral ligands (NCMe, tetrahydrothiophene, SPPh3, PPh3). The structure of [N(PPh3)2][Pt2(µ-I)(µ-dppm)(C6F5)4]·2CHCl3 has been determined by a single-crystal X-ray diffraction study, showing strain in the bridging (µ-X)(µ-dppm) system. Crystals are triclinic, space group P, with a= 11.609(2), b= 19.113(2), c= 19.997(2)Å, α= 101.83(1), β= 93.32(1), γ= 92.61(1)°, Z= 2; 8052 data with I > 3σ(I) refined to R= 0.051, R′= 0.068." @default.
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- W2013025746 date "1993-01-01" @default.
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- W2013025746 title "Binuclear pentafluorophenyl complexes containing halide and/or bis(diphenylphosphino)methane (dppm) as bridging ligands. Molecular structure of [N(PPh3)2][Pt2(µ-I)(µ-dppm)(C6F5)4]·2CHCL3" @default.
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- W2013025746 doi "https://doi.org/10.1039/dt9930001107" @default.
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