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- W2013026652 abstract "Temperature gradient interaction chromatography (TGIC) is applied to the characterization of polyisoprene (PI) and polystyrene (PS) using normal-phase (NP) stationary phase--bare silica or diol bonded silica. Tetrahydrofuran-isooctane mixtures are used as a mobile phase. PI and linear and star shaped PS samples are successfully fractionated in terms of the molecular mass with a high resolution comparable to that of reversed-phase (RP) HPLC. Temperature dependence of the retention shows that the enthalpy of adsorption of PS to the stationary phase is exothermic. In addition, some characteristic features of the NP-TGIC system relative to those of RP-TGIC are presented, which include a high sensitivity on the polar end group and the simultaneous size-exclusion chromatographic and TGIC characterization of PS and PI mixtures." @default.
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- W2013026652 date "2001-02-01" @default.
- W2013026652 modified "2023-10-11" @default.
- W2013026652 title "Characterization of polystyrene and polyisoprene by normal-phase temperature gradient interaction chromatography" @default.
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- W2013026652 doi "https://doi.org/10.1016/s0021-9673(00)01163-8" @default.
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