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- W2013031912 abstract "The primary aim of this paper is to explore the influence of the number of CH2 groups per –(CH2)nOCOO– repeat unit (Numc) on the properties of poly(alkylene carbonate)s. A series of poly(alkylene carbonate)s with different Numc, including PTMC (Numc = 3), PTeMC (Numc = 4), PPMC (Numc = 5), PHMC (Numc = 6) and PDMC (Numc = 10) were investigated for that purpose by DSC and XRD techniques. The method of Sn(Oct)2-catalyzed ring-opening polymerization was developed to prepare poly(pentamethylene carbonate)s (PPMC), which presented a controllable feature. Regarding crystallization rate and Tm of poly(alkylene carbonate)s, an interesting odd–even effect was first reported related to the Numc. The order of crystallizing ability of poly(alkylene carbonate) was: PTMC (Numc = 3) < PPMC(Numc = 5) < PTeMC (Numc = 4) < PHMC (Numc = 6) < PDMC (Numc = 10). Poly(alkylene carbonate)s characterized with even Numc appeared to readily crystallize relative to that with odd Numc." @default.
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- W2013031912 date "2010-03-01" @default.
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- W2013031912 title "Controllable preparation of poly(alkylene carbonate)s and observation on their structure-related odd–even effect" @default.
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- W2013031912 doi "https://doi.org/10.1016/j.polymer.2010.01.009" @default.
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