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• W2013033043 abstract "Abstract Structural modulations of NiAs-Ni 2 In type structures within the B8 phase field of the Ni-Ge system have been investigated with electron diffraction. The modulations of the average B8 substructure (caused by ordering of interstitial Ni atoms in trigonal bipyramidal sites) can in reciprocal space be described by H = G +m q , where G are the Bragg reflections corresponding to the P6 3 /mmc average substructure, m is an integer and q is a primary modulation-wave vector of the form [h,h,2h,l]*. Ni 5 Ge 3 is described by q = 1 / 3 [1122]* which corresponds to a =11.682(6) A, b =6.737(3) A, c =6.264(3) A, b =52.11(1)° and space group C2/c. Ni 19 Ge 12 and Ni 17 Ge 12 are both described by q = 1 / 6 [2243]*. They are each others antistructure with respect to the interstitial sites and have hence identical primary modulation-wave vectors. Ni 7 Ge 4 exhibits a complicated diffuse distribution partly condensed out at q 1 ≈0.18[2243]* and q 2 ≈0.27[1122]*. The diffuse scattering resembles the undulating channels along c * previously observed for Co 1+ x Sn and Ni 1+x Sn but in Ni 7 Ge 4 two independent sets, cutting through q 1 and q 2 respectively, are present." @default.
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• W2013033043 date "1998-01-01" @default.
• W2013033043 modified "2023-09-24" @default.
• W2013033043 title "An electron diffraction study of modulated Ni1+xGe B8 type phases" @default.
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• W2013033043 doi "https://doi.org/10.1016/s0925-8388(97)00254-5" @default.
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