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• W2013039781 endingPage "1312" @default.
• W2013039781 startingPage "1299" @default.
• W2013039781 abstract "The freezing phase transition in a binary suspension of colloidal hard spheres of diameter ratio α=0.61 was studied by light scattering and scanning electron microscopy. The suspensions consisted of sterically stabilized poly(methyl methacrylate) spheres of diameters about 670 and 407 nm suspended in a near refractive indexed matched suspension medium composed of carbon disulphide and cis-decalin. With increasing volume fraction, binary suspensions of number fraction of larger component A xA&gt;0.43 crystallized to give irregularly stacked close packed crystals containing almost entirely component A. As the number fraction xA decreased, the rate of crystallization decreased. Suspensions of xA≊0.28 remained amorphous and showed glassy behavior. Suspensions of xA≊0.057 showed a complex sequence of phase behavior with coexistence of crystals of component B, the ordered binary alloy phase AB13, and a binary fluid. In suspensions with xA&lt;0.057, the only solid phase observed was irregularly stacked close packed crystals of component B. The observed phase behavior is compared with the predictions of a model for freezing of a mixture of hard spheres which are assumed to be immiscible in the solid phase." @default.
• W2013039781 created "2016-06-24" @default.
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• W2013039781 date "1990-07-15" @default.
• W2013039781 modified "2023-10-14" @default.
• W2013039781 title "Freezing of binary mixtures of colloidal hard spheres" @default.
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• W2013039781 doi "https://doi.org/10.1063/1.459142" @default.
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