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• W2013044263 abstract "Three bis(tacn) ligands 3,5-bis(1,4,7-triazacyclonon-1-ylmethyl)biphenyl (Lphx) (1), 3,5-bis(1,4,7-triazacyclonon-1-ylmethyl)benzoic acid (Lcax) (2) and 3,5-bis(1,4,7-triazacyclonon-1-ylmethyl)-nitrobenzene (Lnix) (3) have been synthesised. Reactions of these ligands with two equivalents of Cu(NO3)2·3H2O in the presence of NaOH and NH4PF6 resulted in crystallisation of three distinct product classes, viz (i) polymeric {[Cu2(μ-Cl)2(Lphx)](PF6)2}n (5) in which the Lphx ligand bridges two Cu2 moieties, (ii) tetranuclear [Cu2(μ-OH)(Lcax)]2(NO3)2(PF6)2·2H2O (6) in which two “head to tail” Lcax ligands chelate to two Cu2 moieties, and (iii) dinuclear [Cu2(μ-OH)(μ-Cl)(Lnix)](NO3)(PF6) (7) where the Lnix ligand chelates to a single Cu2 centre." @default.
• W2013044263 created "2016-06-24" @default.
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• W2013044263 date "2014-02-01" @default.
• W2013044263 modified "2023-10-18" @default.
• W2013044263 title "Metal complexes of new bis(tacn) ligands: Syntheses and structures of copper(II) complexes" @default.
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• W2013044263 doi "https://doi.org/10.1016/j.poly.2013.11.037" @default.
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