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- W2013048992 abstract "A facile one-pot sequential conjugate addition/dearomative fluorination transformation of isoxazol-5(4H)-ones with nitroolefins and N-fluorobenzenesulfonimide (NFSI) has been developed. By using a bifunctional chiral tertiary amino-thiourea catalyst, a series of chiral fluorinated isoxazol-5(4H)-ones containing one fluorine-substituted quarternary stereocenter were obtained in high yields with high enantio- and diastereoselectivities. Further transformation of adducts could afford isoxazolidin-5-one derivatives with three contiguous stereocenters." @default.
- W2013048992 created "2016-06-24" @default.
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- W2013048992 date "2012-12-18" @default.
- W2013048992 modified "2023-10-18" @default.
- W2013048992 title "Organocatalytic Asymmetric One-Pot Sequential Conjugate Addition/Dearomative Fluorination: Synthesis of Chiral Fluorinated Isoxazol-5(4<i>H</i>)-ones" @default.
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- W2013048992 doi "https://doi.org/10.1021/jo302419e" @default.
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