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• W2013058803 abstract "A Chinese high-rank coal was acid-washed and ion-exchanged with Na and K to prepare the H-form, Na-form and K-form coals. After pyrolysis, H-form, Na-form and K-form chars and two additional H-form chars (acid washed Na-form and K-form chars) were prepared to investigate the effects of alkaline metal (AM) on coal gasification at the pyrolysis and gasification phases. The H-form char had the highest pryolysis rate; the H-form char had a relative low gasification rate. The AM loaded coals exhibited relative low pyrolysis rate, while the corresponding chars had high gasification reactivity. Acid-washing reduced the reactivities of Na-form and K-form chars. AM inhibited the progress of graphitization of the base carbon resulting in a more reactive char of less ordered crystalline carbon structure. A kinetic model incorporating AM-catalyzed gasification and non-catalytic gasification was developed to describe the gasification rate changes in the char conversion for AM-catalyzed gasification of chars." @default.
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• W2013058803 date "2011-05-01" @default.
• W2013058803 modified "2023-09-25" @default.
• W2013058803 title "Effects of alkaline metal on coal gasification at pyrolysis and gasification phases" @default.
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• W2013058803 doi "https://doi.org/10.1016/j.fuel.2011.01.033" @default.
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