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• W2013077897 startingPage "910" @default.
• W2013077897 abstract "Abstract The first total synthesis of (+)‐neomarinone has been achieved by following a concise and convergent route using methyl ( R )‐lactate and ( R )‐3‐methylcyclohexanone as chiral building blocks. Key steps of the synthesis are the stereocontrolled formation of the two quaternary stereocenters by diastereoselective 1,4‐conjugate addition and enolate alkylation reactions, and the construction of the furanonaphthoquinone skeleton by regioselective Diels–Alder reaction between a 1,3‐bis(trimethylsilyloxy)‐1,3‐diene and a bromoquinone. The synthesis proves the relative and absolute stereochemistry of natural neomarinone." @default.
• W2013077897 created "2016-06-24" @default.
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• W2013077897 date "2009-01-05" @default.
• W2013077897 modified "2023-10-18" @default.
• W2013077897 title "Total Synthesis of (+)-Neomarinone" @default.
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• W2013077897 doi "https://doi.org/10.1002/chem.200802021" @default.
• W2013077897 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19053110" @default.
• W2013077897 hasPublicationYear "2009" @default.
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