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- W2013078307 abstract "Abstract In order to find a short entry into azabicycloheptanes we have studied the High Pressure promoted cycloadditions of N-acylpyrroles with dienophiles in the pressure range 9-18 Kbar. At pressures above 9 Kbar N-acylpyrroles react with bis-activated dienophiles such as N-phenylmaleimide. Above 15 Kbar also mono activated dienophiles react with a variety of N-acylpyrroles. The cycloadditions are sometimes accelerated by pressure in a narrow pressure range. Special attention has also been paid to the effects of solvent and temperature on these reactions. The large differences in solvent effects have been explained by pressure depended solubility of the dienophile." @default.
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- W2013078307 date "1991-12-15" @default.
- W2013078307 modified "2023-09-26" @default.
- W2013078307 title "High pressure diels-alder reactions of pyflroles. Influence of pressure solvent and pyrrole-substituents on the conversion rate" @default.
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- W2013078307 doi "https://doi.org/10.1080/08957959108245524" @default.
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